Problem

(a) Give equations to show the effect of temperature on the reaction between Cl2 and aqueo...

(a) Give equations to show the effect of temperature on the reaction between Cl2 and aqueous NaOH.


(b)     In neutral solution 1 mol [IO4]~ reacts with excess 1“ to produce 1 mol I2. On acidification of the resulting solution, a further 3 mol T2 is liberated. Derive equations for the reactions which occur under these conditions.


(c)            In strongly alkaline solution containing an excess of barium ions, a solution containing 01587 g of 1" was treated with 0.1m [MnO4] until a pink colour persisted in the solution; 10.0cm' was required. Under these conditions, [MnO4]­ was converted into the sparingly soluble BaMnO4. What is the product of the oxidation of iodide?

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Solutions For Problems in Chapter 17