When an ethyl group (CH3CH2-) is bonded to a cyclohexane ring, 96% of the molecules possess an equatorial CH3CH2- group at equilibrium. When an ethynyl group (HC ≡ C-) is bonded to a cyclohexane ring, only 67% of the molecules possess an equatorial HC=C- group at equilibrium. Suggest a reason for this difference.
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