The reactions of ozone were studied in the presence of alkenes [R. Atkinson
et al., Int. J. Chem. Kinet., 15(8), 721 (1983)]. The data in Table PS-11 are for
one of the alkenes studied, cis-2-butene. The reaction was carried out isothermally
at 297 K. Determine the rate law and the values of the rate law parameters.
Run | Overall Ozone Decomposition Rate (mol/s.dm3X 107) | Ozone Concentration (mol/dm3) | Butene Concentration (mol/dm3) |
1 | 1.5 | 0.01 | 10-12 |
2 | 3.2 | 0.02 | 10-11 |
3 | 3.5 | 0.015 | 10-10 |
4 | 5.0 | 0.005 | 10-9 |
5 | 8.8 | 0.001 | 10-8 |
6 | 4.7 | 0.018 | 10-9 |
(Hint: Ozone also decomposes by collision with the wall.)
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