Problem

(a) A five-atom linear molecule is simulated by a configuration of masses and ideal spring...

(a) A five-atom linear molecule is simulated by a configuration of masses and ideal springs that looks like the following diagram:

All force constants are equal. Find the eigenfrequencies and normal modes for longitudinal vibrations. [Hint: Transform the coordinates ηi to ζi defined by

with symmetrical expressions for η2 and η4. The secular determinant will then factor into determinants of lower rank.]


(b) Solve this problem using computer techniques.

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Solutions For Problems in Chapter 6