Consider the reaction between NO2 and N2O4 in a closed container:
Initially, 1 mole of N2O4 is present. At equilibrium, xmole of N2O4 has dissociated to form NO2. (a) Derive an expression for Kp in terms of x and P, the total pressure. (b) How does the expression in part (a) help you predict the shift in equilibrium due to an increase in P? Does your prediction agree with Le Châtelier’s principle?
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