Problem

For the molecule PCl5: a. Using the character table for the point group of PCl5, de...

For the molecule PCl5:

a. Using the character table for the point group of PCl5, determine the possible type(s) of hybrid orbitals that can be used by P in forming σ bonds to the five Cl atoms.

b. What type(s) of hybrids can be used in bonding to the axial chlorine atoms? To the equatorial chlorine atoms?

c. Considering your answer to part b, explain the experimental observation that the axial P–Cl bonds (219 pm) are longer than the equatorial bonds (204 pm).

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Solutions For Problems in Chapter 5