At 25° C the reaction
has Kp = 0.120. A 5.00-L flask is charged with 0.300 g of pure H2S(g) at 25 °C. Solid NH4HS is then added until there is excess unreacted solid remaining. (a) What is the initial pressure of H2S(g) in the flask? (b) Why does no re-action occur until NH4HS is added? (c) What are the partial pressures of NH3 and H2S at equilibrium? (d) What is the mole fraction of H2S in the gas mixture at equilibrium? (e) What is the minimum mass, in grams, of NH4HS that must be added to the flask to achieve equilibrium?
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