Problem

Some Vm versus P data for CH4(g) at −50°C are P/atm510204060Vm/(cm3/mol)35771745828365206...

Some Vm versus P data for CH4(g) at −50°C are

P/atm

5

10

20

40

60

Vm/(cm3/mol)

3577

1745

828

365

206

For the virial equation (8.4) with terms after C omitted, use a spreadsheet to find the B and C values that minimize the sums of the squares of the deviations of the calculated pressures from the observed pressures.

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Solutions For Problems in Chapter 8