Write balanced equations for the reactions of aqueous Ga with [I3]_, Br2, [Fe(CN)f,]3- and [Fe(bpy)3]3_.
The 205 T1 NMR spectrum of an acidic solution that contains Tl3+ and 13C-enriched [CN]_ ions in concentrations of 0.05 and 0.31 mol dm 3 respectively shows a binomial quintet (8 3010 ppm, J— 5436 Hz) and quartet (8 2848 ppm, 7=7954 Hz). Suggest what species are present in solution and rationalize your answer. (See Table 4.3 for nuclear spin data.)
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