The titration of Fe(II) with permanganate yields a particularly asymmetrical titration curve because of the different number of electrons involved in the two half-reactions. Consider the titration of 25.00 Ml of 0.1 M Fe(II) with 0.1 M MnO4- . The H+ concentration is maintained at 1.0 M throughout the titration. Use a spreadsheet to generate a theoretical titration curve and a first and second derivative plot. Do the inflection points obtained from the maximum of the first derivative plot or the zero crossing of the second derivative plot correspond to the equivalence point? Explain why or why not.
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