Problem

Use an apparatus similar to that shown in Figure 14.1 and assume that the roundbottom fl...

Use an apparatus similar to that shown in Figure 14.1 and assume that the roundbottom flask holds 100 mL and the distilling head has an internal volume of 12 mL in the vertical section. At the end of a distillation, vapor would fill this volume, but it could not be forced through the system. No liquid would remain in the distillation flask. Assuming this holdup volume of 112 mL, use the ideal gas law and assume a boiling point of 100 C (760 mmHg) to calculate the number of milliliters of liquid (d =0.9 g/mL, MW =200) that would recondense into the distillation flask upon cooling.

(For Reference Figure 14.1)

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Solutions For Problems in Chapter T14