Problem

We often need to estimate the pressures and volumes of a gas in a container. The van der W...

We often need to estimate the pressures and volumes of a gas in a container. The van der Waals equation is often used for this purpose. It is

where the term b is a correction for the volume of the molecules, and the term  is a correction for molecular attractions. The gas constant is R, the absolute temperature is T, and the gas specific volume is . The value of R is the same for all gases; it is R = 0.08206 L-atm/mol-K. The values of a and b depend on the type of gas. Some values are given in the following table. Write a user-defined function using the switch structure that computes the pressure P on the basis of the van der Waals equation. The function’s input arguments should be T, , and a string variable containing the name of a gas listed in the table. Test your function for chlorine (Cl2) for T = 300 K and  = 20 L/mol

Gas

a (L2-atm/mol2)

b (L/mol)

Helium, He

    0.0341

0.0237

Hydrogen, H2

  0.244

0.0266

Oxygen, O2

1.36

0.0318

Chlorine, Cl2

6.49

0.0562

Carbon dioxide, CO2

3.59

0.0427

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Solutions For Problems in Chapter 4