Problem

A sample calculation in this chapter showed that, according to Slater’s rules, a 3 d ele...

A sample calculation in this chapter showed that, according to Slater’s rules, a 3 d electron of nickel has a higher effective nuclear charge than a 4 s electron. Is the same true for early first-row transition metals? Using Slater’s rules, calculate S and Z * for 4 s and 3 d electrons of Sc and Ti, and comment on the similarities or differences with Ni.

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Solutions For Problems in Chapter 2