Problem

The following gas-phase reaction was studied at 290°C by observing the change in pressure...

The following gas-phase reaction was studied at 290°C by observing the change in pressure as a function of time in a constant-volume vessel:

Determine the order of the reaction and the rate constant based on the following data.

Time (s)

P(mmHg)

0

15.76

181

18.88

513

22.79

1164

27.08

where P is the total pressure.

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