Problem

Figure 3.26 shows the first five peaks of the x-ray diffraction pattern for tungsten (W),...

Figure 3.26 shows the first five peaks of the x-ray diffraction pattern for tungsten (W), which has a BCC crystal structure; monochromatic x-radiation having a wavelength of 0.1542 nm was used.

(a) Index (i.e., give h, k, and l indices) each of these peaks.

(b) Determine the interplanar spacing for each of the peaks.

(c) For each peak, determine the atomic radius for W, and compare these with the value presented in Table 3.1.

Figure 3.26 Diffraction pattern for powdered tungsten. (Courtesy of Wesley L. Holman.)

Table 3.1 Atomic Radii and Crystal Structures for 16 Metals

Metal

Crystal Structurea

Atomic Radiusb (nm)

Metal

Crystal Structure

Atomic Radius (nm)

Aluminum

FCC

0.1431

Molybdenum

BCC

0.1363

Cadmium

HCP

0.1490

Nickel

FCC

0.1246

Chromium

BCC

0.1249

Platinum

FCC

0.1387

Cobalt

HCP

0.1253

Silver

FCC

0.1445

Copper

FCC

0.1278

Tantalum

BCC

0.1430

Gold

FCC

0.1442

Titanium (α)

HCP

0.1445

Iron (α)

BCC

0.1241

Tungsten

BCC

0.1371

Lead

FCC

0.1750

Zinc

HCP

0.1332

aFCC = face-centered cubic; HCP = hexagonal close-packed; BCC = body-centered cubic.

bA nanometer (nm) equals 10–9 m; to convert from nanometers to angstrom units (Å), multiply the nanometer value by 10.

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