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Determine the equilibrium constant, Kgoal, for the reaction 4PCl5(g)⇌P4(s)+10Cl2(g),    Kgoal=? by making use of the following information:...

Determine the equilibrium constant, Kgoal, for the reaction

4PCl5(g)⇌P4(s)+10Cl2(g),    Kgoal=?

by making use of the following information:

P4(s)+6Cl2(g)⇌4PCl3(g),       K1=2.00×1019

PCl5(g)⇌PCl3(g)+Cl2(g),       K2=1.13×10−2

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Answer #1

4PCl3(g) ⇌ P4(s)+6Cl2(g)   1/ k1 = 1/(2*10^19)

4* (PCl5(g)⇌PCl3(g)+Cl2(g) ) K2 = (1.13*10^(-2))^4

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4PCl5(g)⇌P4(s)+10Cl2(g),    Kgoal=1/ k1*k2

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    = (1/(2*10^19))*(1.13*10^(-2))^4

   = 8.15*10^-28

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