Question

1A)

Determine the value of the equilibrium constant, Kgoal, for the reaction

CO2(g)⇌C(s)+O2(g),     Kgoal=?

by making use of the following information:

1. 2CO2(g)+2H2O(l)⇌CH3COOH(l)+2O2(g),	K1 =	5.40×10−16
2. 2H2(g)+O2(g)⇌2H2O(l),	K2 =	1.06×1010
3. CH3COOH(l)⇌2C(s)+2H2(g)+O2(g),	K3 =	2.68×10−9

1B)

Determine the equilibrium constant, Kgoal, for the reaction

4PCl5(g)⇌P4(s)+10Cl2(g),    Kgoal=?

by making use of the following information:

1. P4(s)+6Cl2(g)⇌4PCl3(g),       K1=2.00×1019
2. PCl5(g)⇌PCl3(g)+Cl2(g),       K2=1.13×10−2

1C)

For a certain reaction, Kc = 8.28×10⁻⁵ and kf= 2.12×10⁻² M−2⋅s−1 . Calculate the value of the reverse rate constant, kr, given that the reverse reaction is of the same molecularity as the forward reaction.

Express your answer with the appropriate units. Include explicit multiplication within units, for example to enter M−2⋅s−1 include ⋅ (multiplication dot) between each measurement.

1D)

For a different reaction, Kc = 3.71×10⁵, kf=2.12×103s−1 , and kr= 5.71×10⁻³ s−1 . Adding a catalyst increases the forward rate constant to 2.97×10⁵ s−1 . What is the new value of the reverse reaction constant, kr, after adding catalyst?

Express your answer with the appropriate units. Include explicit multiplication within units, for example to enter M−2⋅s−1 include ⋅ (multiplication dot) between each measurement.

1E)

Yet another reaction has an equilibrium constant Kc=4.32×105 at 25 ∘C. It is an exothermic reaction, giving off quite a bit of heat while the reaction proceeds. If the temperature is raised to 200 ∘C , what will happen to the equilibrium constant?

The equilibrium constant will

increase.

decrease.

not change.

Sorry for the long question :( I didn't wanna split the parts up since they seemed related and might have crucial info for completing the next part.

Thank you in advance!

Answer 1