Give the products (if any) expected from the treatment of each of the following compounds with ozone followed by aqueous hydrogen peroxide. Do not draw any byproducts.
a) 2-methyl-2-pentene
b) cyclooctene
a) products formed are: Acetone (Propan-2-one) and Propan-1-al.
b) product will be Octan-1,8-dioic acid
Give the products (if any) expected from the treatment of each of the following compounds with ozone followed by aqueous hydrogen peroxide
Give the products (It any) expected from the treatment of each of the following compounds with ozone followed by aqueous hydrogen peroxide. Do not draw any byproducts.
Give the products (if any) expected from the treatment of each of the following compounds with ozone followed by dimethyl sulfide.A. 3-methyl-2-pentane _______ + (CH3)2SOB. _______ + (CH3)2SO
Give the products (if any) expected from the treatment of each of the following compounds with ozone followed by dimethyl sulfide.
[Review Topical [References) 1-Butene reacts with borane in THF followed by hydrogen peroxide in aqueous NaOH to give A (CH100). Treatment of A with aqueous chromic acid or Cro, in acetic acid gives B (C,H,O,). Draw the structure of B. • You do not have to consider stereochemistry. . In cases where there is more than one answer, just draw one. ChemDoodle [Review Topics) [References) A (CzH,0) reacts rapidly with ethylmagnesium bromide in anhydrous ether to give B (C,H,20). Treatment...
for alkenes A,B,C, draw the products formed when each alkene is treated with ozone, followed by Zn, H2O. Be sure to answer all parts For alkenes A, B, and C, draw the products formed when each alkene is treated with ozone, followed by Zn, H2O. Be sure to answer all parts.
10. On treatment with excess of sodium borohydride in methanol followed by treatment with aqueous acid, which of the following carbonyl compounds is expected generate a racemic mixture of alcohols? CH, DO U 7. Starting with the compound with lowest pKa (t.e. most acidic), arrange the following in the order of increasing pKa values. OH (A) X <Y <Z <W (B) Z < X<Y <W (C) Y <Z < X <W (D) W < X <Y <Z (E) Z <Y...
3. When compound A is reacted with BH3•THF in a first step and basic hydrogen peroxide in a second step 3-methyl-2-hexanol is obtained. When compound A is heated with acidic potassium permanganate two products (B and C) are obtained. When compound A is reacted with HBr a compound D is obtained. Draw the structures for compounds A, B, C and D. (40 points)
Draw the structure resulting froma reaction of 1. diborane (B2H), followed by 2. alkaline hydrogen peroxide (NaOH/H2O,) with the following alkene. . Use the wedge hash bond tools to indicate stereochemistry where it exists. If a group is achiral, do not use wedged or hashed bonds on it If the reaction produces a racemic mixture, just draw one stereoisomer
2. Write the major organic product expected from each of the following reactions: (120 pts) (a) CH&CH CH2Br+ NaOH in acetone solvent (b) 1-methylcyclopentene + HCI (c) cyclopentanol+ H2SO4+heat (e) 1-pentyne+H2O H2SO4 (8) benzene + methyl iodide+AICI (i) 2-methyl-1-pentene+ BHo, then HOOH and NaOH () 2-bromobutane + CH,CH,ONa in ethanol (d) 1-pentene + HBr with trace peroxide (f) 1,2-bromopentane + NaNH2 in liquid ammonia (h) ethylbenzene + HNO, + HSO