Question

Draw the products of the complete hydrolysis of a ketal. Draw all products of the reaction.

Image for Draw the products of the complete hydrolysis of a ketal. Draw all products of the reaction.

Draw the products of the complete hydrolysis of a ketal. Draw all products of the reaction.
1 0
Add a comment Improve this question Transcribed image text
✔ Recommended Answer
Answer #1
Concepts and reason

The concept used is to draw the products of the hydrolysis of a ketal.

Fundamentals

A compound that contains two alkoxy group bonded to the same carbon atom is a ketal. The general structure of ketal is R2C(OR’)2, here R is alkyl or aryl.

A compound that contains one alkoxy group and one hydroxyl group bonded to the same carbon atom is a hemiacetal.

Protection of carbonyl compounds produces acetals and ketals.

Ketals can be hydrolyzed by the aqueous acidic medium.

Hydrolysis of ketals in the presence of acidic medium produces hemi-acetal. The reaction is as follows:

CH3
H3CH2
H5C ос?
с
H,
+
+
н,
7
с
н
Н,
Но-с*
7
.
H2
.
н
+
C-CH3
н,с о
н,сон
H3 CH3
с
—СН,
CH,
H2
+
но.
CH,
H5C он
с Н,
н,с о

Hydrolysis of hemiacetal in the presence of acidic medium produces carbonyl compound and corresponding alcohol. The reactions are as follows:

HzC, 0-c-CH3
с н,
н,сон
+
,
о
7
н
—
*
H,C
С=0
HOSCH3
+
СН3
СН3
H3C
H,C он
н,c occ-CH3 +
с=0
С
,
=0
с.
+
н*
носо-СН3
,
н,
н”
н

Ans:

The reaction showing all products is as follows:

CH3
H5C oc
HC
H,
н,
на на
С=0
+
НОРc-CH,
нс
04
Hzc orc-CH3
СН3
Сн,
н,
+
HO-
CH3

Add a comment
Know the answer?
Add Answer to:
Draw the products of the complete hydrolysis of a ketal. Draw all products of the reaction.
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for? Ask your own homework help question. Our experts will answer your question WITHIN MINUTES for Free.
Similar Homework Help Questions
ADVERTISEMENT
Free Homework Help App
Download From Google Play
Scan Your Homework
to Get Instant Free Answers
Need Online Homework Help?
Ask a Question
Get Answers For Free
Most questions answered within 3 hours.
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT