Three isomeric ketones, compounds A, B, and C, with the molecular formula C_7H_14O are converted into...
True and False questions!!
1. True and False Question (1) Carbonyl compounds have higher boiling points than hydrocarbons, but lower boiling points than corresponding alcohols. (2) Aldehydes and ketones react with primary amines to form imines and with secondary amines to form enamines. (3) Aldehydes and ketones can be oxidized to carboxylic acids. (4) Diols can form acetal with the ketone or aldehyde to protect them for selective reduction of the ester (5) The electron-withdrawing group in Wittig reagent does...
1. True and False Question (0.5 point per question) a) Carbonyl compounds have higher boiling points than hydrocarbons, but lower boiling points than corresponding alcohols. b) Aldehydes and ketones react with primary amines to form imines and with secondary amines to form enamines. c) Aldehydes and ketones can be oxidized to carboxylic acids. d) Diols can form acetal with the ketone or aldehyde to protect them for selective reduction of the ester. e) The electron-withdrawing group in Wittig reagent does...
Three bottles A, B, and C have been found, each of which contains a
liquid and is labeled \"amine C8H11N.\" As an expert in amine
chemistry, you have been hired as a consultant and asked to
identify each compound. Compounds A and B give off a gas when they
react with NaNO2 and HCl at 0 ℃; C does not. However, when the
aqueous reaction mixture from the diazotization of C is warmed, a
gas is evolved. Compound A is...
21-Ketones are easily reduced to secondary alcohols. b- Primary CH, CCH, a-Secondary alcohol alcohol C- to acetaldehyde acid d-to carboxylic 22-Ozonolysis of alkenes yields aa-ketones if one of the unsaturated carbon atoms is disubstituted b-alcohol C-carboxylic acid d-alkane 23-Aldehyde C=0 is more polarized than ketone C-0 because a-As in carbocations, more alkyl groups stabilize + character b-Ketone has more alkyl groups, stabilizing the C=0 carbon inductively cc- due to a and b d- none of the above 24-Aldehydes and unhindered...
Organic compound X, with molecular formula C11H1403, undergoes complete oxidation with solution of potassium permanganate acidified with sulfuric acid and gives only three (3) organic products A, B and C. For each of the products A, B and C the following are given below: Union A With an alkaline solution of iodine, it gives a yellow precipitate. Compound B It is volatile and is therefore widely used as a solvent in dyes. Reduction of compound B, under the appropriate conditions,...
I need help on these 3 questions please
b. There are four isomeric alkyl bromides derived from the two dit (above) with the formula C.H.Br. draw a structural formula for an To The two different butane isomers la for all four compounds. 3. Draw a structural formula for all the isomers of hexane, C.H. You may draw complete structural formulas, condensed formulas or line drawings. Hint: there are five isomers. 4. Write the molecular formula for the following structures. One...
Road map: A, B, and C are cyclic alkyl halides with a molecular formula of C6H11Br. Compound B reacts with Na+ - OCH3 in DMSO at room temperature to give the corresponding ether D. Compound C reacts with Na+ - OCH3 in DMSO to give a different ether E and cyclic trisubstituted alkene F. Compound B reacts much faster with Na+ -OCH3 in DMSO than compound C. Compound A does not give an ether when reacted with Na+ -OCH3 in...
Organic compound X, with molecular formula C11H14O3, undergoes complete oxidation with solution of potassium permanganate acidified with sulfuric acid and gives only three (3) organic products A, B and C. For each of the products A, B and C the following are given below: Union A With an alkaline solution of iodine, it gives a yellow precipitate. Compound B It is volatile and is therefore widely used as a solvent in dyes. Reduction of compound B, under the appropriate conditions,...
Reaction of compound A, formula C_8H_14O, with the Wittig reagent CH_2=P(C_6H_5)_3 produces compound B, C_9H_16. Treatment of compound A with LiAlH_4 yields two diastereomeric products C and D, both C_8H_16O, in unequal yields. Heating either C or D with concentrated sulfuric acid produces compound E, with the formula C_8H_14. Ozonolysis of E produces a keto aldehyde. Oxidation of this keto aldehyde with chromic acid produces: Identify compounds A through E. Pay particular attention to the stereochemistry.
8. Following are the 'Handic spectra for two isomeric hromalkancs, A and B (compon following page) with molecular formula C.H.Br. Draw their structure. (compound B is on the 1Η COCI (Solvent) www wwwwwwwwwwwwww 95 90 85 80 75 70 wwww 60 55 50 45 65 40 35 30 25 20 15 10 CDCI (Solvent) TMS 95 90 RS 80 75 70 65 60 55 50 45 40 35 30 25 20 15 10 5 0 -5 -10