16. a) (4 points) Propose a mechanism for the following isomerization reaction: OH H3O+ ОН b)...
ompound A readily isomerizes to compound B in the presence of trace amounts of base он NaOH EtOH он a.) Give a mechanism to explain how this isomerization takes place. (8 points b.) Given the fact that A isomerizes to B, what does this tell you about the relative energies (free energy) of the two compounds? Briefly explain why they have this energetic relationship. (4 points)
ompound A readily isomerizes to compound B in the presence of trace amounts of...
7. Propose a mechanism for the following transformation: Å Ho 8. Propose a plausible mechanism for the following isomerization and explain why the equilibrium favors the product. OH 9. Cinnamaldehyde is one of the primary components of cinnamon oil. Propose TWO separate syntheses of cinnamaldehyde from benzene and any organic material with less than three carbons cinnamaldehyde
8. Draw an arrow-pushing mechanism to show the alkene isomerization from to B CH3 cat. H3O* A B A Draw the reaction coordinate diagram for the reaction above from A to B. reaction coordinate Regardless of the ratio of A to B at equilibrium, when the above transformation is run dilute in H2O at lower temperature, another product forms as the major product. Draw that product below. Free Enely
8. Draw an arrow-pushing mechanism to show the alkene isomerization from...
Propose a mechanism for the following reaction:
PLEASE EXPLAIN!
is • (4 points) Propose a mechanism for the following reaction: > HO H+, H2O switch
Write an arrow formalism mechanism for the following reaction. Explain why 1 is formed, but 2 is not. Он Н,о Н.о OH Be sure to give us two reasons why the OH winds up adjacent to the ring and not on the other carbon of the starting allkene. он H3O* Н.о 2
4. Propose a mechanism for the following reaction. Br Br2 ОН 7
6. Propose a mechanism for the following reaction under conditions that favor a SN1 reaction. (16 points) HO X ОН Br
Practice Problem 12.38 Propose a mechanism for the following reaction: BrMV он OH Nah 12.38a1 Draw step 1 of the mechanism using curved arrows. Include lone pairs and charges in your answer. н Edit I
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/H20 Qestion 5 (6 points) Propose a synthesis for the target compound with given starting materials. You may use additional reagents you need. The proposed synthesis should be no more than S steps. Hint: Enolate Reaction, Decarboxylation Reaction. Target Compound Starting Materials
Question 4 (10 points) Draw mechanism for the following reactions: -OH a) HO_ Ht 1. Mel b) 2. H'/H20
Qestion...
Please solve for all steps. Please write clearly and large
enough. Thank you.
Draw a stepwise mechanism for the following reaction. 0.5 points он eBook Print Reference OH draw structure draw structure draw structure
Draw a stepwise mechanism for the following reaction. 0.5 points он eBook Print Reference OH draw structure draw structure draw structure