Question

Consider the following reaction:

2NO2(g) ⟶ N2O4(g)

Part B Calculate AG at 298 K if the partial pressures of NO2 and N204 are 0.39 atm and 1.62 atm , respectively. Express the f

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Answer #1

first calculate Kp of the reaction

Kp = (PN2O4) / (PNO2)2

Kp = (1.62) / (0.39)2 = 1.62 / 0.1521

Kp = 10.65

now

\DeltaG = - RTlnK

R = 8.314 J/molK

T = 298 K

K = 10.65

\DeltaG = - 8.314 x 298 x ln 10.65

\DeltaG = - 5860 J

\DeltaG = 5.86 kJ

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