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![Overall reaction: 2NO + Cl₂ → 2Noce Rate law : Rate = k [no] [ll 2] following mechanisms are possible as per the above mentio](http://img.homeworklib.com/questions/d7d65560-6e99-11ea-8c27-559e111307c1.png?x-oss-process=image/resize,w_560)
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select all of the mechanisms that are plausible for a given
reaction and it's experimentally determined...
Select all that apply. The rate law for the reaction 2NO(g) + Cl2(g) → 2NOCI(g) is...
Select all that apply. The rate law for the reaction 2NO(g) + Cl2(g) → 2NOCI(g) is given by R-k[NO][C121 If the following is the mechanism for the reaction, NO(g) + Cl2(g) → NOC12(g) NOCI,(g) + NO(g) → 2NOCI(g) which of the following statements accurately describes this reaction? Check all that apply. 2nd order reaction The first step is the slow step. Doubling [NO] would quadruple the rate. Cutting (Cl) in half would decrease the rate by a factor of two....
Propose a plausible two-step mechanism for the given reaction (Pool: 5 of 5) Propose a plausible...
Propose a plausible two-step mechanism for the given reaction (Pool: 5 of 5) Propose a plausible two-step mechanism for the reaction given below with the steps provided. Overall Reaction: 2A + 2B rightarrow C + D Experimentally Determined Rate Law: rate = K[A][B]^2 Two-Step Mechanism: Step 1: Step 2:
5. The reaction 2NO+ Cl2 → 2NOCI is thought to occur in two steps, as shown...
5. The reaction 2NO+ Cl2 → 2NOCI is thought to occur in two steps, as shown by the following proposed mechanism: O NO + Cl2 NOCI (fast, at equilibrium) (i) NO + NOCI, → 2NOCI (slow) What rate law does this mechanism predict? Select the best choice by circling it. a. rate = ** [NO]?[NOCI] rate = *, [NO]2 C. rate = [NOCL] d. rate = kek [NO](C1,12 rate = [NO] f. rate = kaka [NO]+[C12] g. rate = kak2...
consider the aqueous reaction of Cl2 + H2S -> S + 2HCL . It may happen...
consider the aqueous reaction of Cl2 + H2S -> S + 2HCL . It may happen by the following mechanism 1: Cl2-> <- 2Cl fast 2: Cl+H2S -> <- HCl + HS fast 3: HS +Cl --> --< HCl + S slow DERIVE a rate law for overall reaction using the given mechanism and rate determining step without using intermediates in the rate law.
The rate equation for the reaction 2NO(g) + Br_2(g) rightgarrow 2NOBr(g) was determined experimentally to be:...
The rate equation for the reaction 2NO(g) + Br_2(g) rightgarrow 2NOBr(g) was determined experimentally to be: Rate = k[NO]^2 [Br_2] Five possible mechanisms have been proposed (i)-(v). Determine the rate equation for each mechanism below and then decide with reasons, (based on the information given) which mechanism is the most likely. (i) 2NO (g) + Br_2 (g) rightarrow 2NOBr (g) (ii)NO (g) + Br_2 rightwardsharpoonoverleftwardsharpoon NOBr_2 (g) NOBr_2 (g) + NO (g) rightarrow 2NOBr (g) (iii) Br_2 rightwardsharpoonoverleftwardsharpoon Br +...
3.(12pts) The reaction Cl(aq) + HS(a) determined DRL S)+(aq) +2 Cl(aq) has the experimentally rate k[Cl2][H2S]...
3.(12pts) The reaction Cl(aq) + HS(a) determined DRL S)+(aq) +2 Cl(aq) has the experimentally rate k[Cl2][H2S] Which of the following mechanisms is(are) consistent with the experimental results. Mech I Mech 11, Mech III Cl2 +H2S >H CI CI+HS (slow) CI+ + HS. …>H+ + Cl. + S H2S = HS. + H+ HSCl2 2CI +S+H (fast) (fast equil) (slow) H2S HS+H (fast equil) (fast equil) (slow) 4. (10 pts) Write the equilibrium constant Ke expression for the following 4 KO:(s)...
Please answer each part with work shown. Thank you. 6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +...
Please answer each part with work shown. Thank you.
6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +NON2+0 (fast) O+H2-> H2O (fast) 2 NO-N202 (fast equilibrium) H2-N202-H20+ N3O (slow) H2+N20-H2O+N2 (fast) H2 + 2 NO- H2O+N2O (slow) N20+ H2N2+ H2O (fast) a) What is the overall reaction that each proposed mechanism supports? b) Calculate the ΔΗ'm for the overall reaction. c) For each mechanism, draw an energy...
13 Interpreting Mechanisms S20(1) - Protected View - Saved - Search References Mailings Review View ain...
13 Interpreting Mechanisms S20(1) - Protected View - Saved - Search References Mailings Review View ain viruses. Unless you need to edit, it's safe stay in Prolus i ew. Enable Editing Student Name: #13 Interpreting Mechanisms 1. Consider the following mechanism: Step 1 Brz Step 2 Br + H2 Step 3 H2Br Br - fast 2Br H2Br 2HBO fast slow a. What is the overall equation? b. Identify the intermediate(s) if any. c. What is the molecularity and the rate...
Rates of Non-elementary reactions Class Activity Consider the following mechanism: 2NO N202 k-1 N...
step by step
Rates of Non-elementary reactions Class Activity Consider the following mechanism: 2NO N202 k-1 NzOz + C12-2+2 NOCI a. What is the net reaction? b. Which of the above species is an intermediate? Why? c. Find the rate of the overall reaction using the steady-state approximation. d. Repeat part (c) using the rate-determining step method, assuming the first-step is fast and at equilibrium and the second step is slow. 2NO N,02 (ast,at equilibrium) k-1 N202 + Cl2-22 NOCI...
Part A Given the following proposed mechanism, predict the rate law for the overall reaction. 2...
Part A Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 → 2 NO2Cl (overall reaction) Mechanism NO2 + Cl2 → NO2Cl + Cl slow NO2 + Cl → NO2Cl fast Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 → 2 NO2Cl (overall reaction) Mechanism NO2 + Cl2 → NO2Cl + Cl slow NO2 + Cl → NO2Cl fast Answer Choices: Rate =...
Select all that apply. The rate law for the reaction 2NO(g) + Cl2(g) → 2NOCI(g) is given by R-k[NO][C121 If the following is the mechanism for the reaction, NO(g) + Cl2(g) → NOC12(g) NOCI,(g) + NO(g) → 2NOCI(g) which of the following statements accurately describes this reaction? Check all that apply. 2nd order reaction The first step is the slow step. Doubling [NO] would quadruple the rate. Cutting (Cl) in half would decrease the rate by a factor of two....
Propose a plausible two-step mechanism for the given reaction (Pool: 5 of 5) Propose a plausible two-step mechanism for the reaction given below with the steps provided. Overall Reaction: 2A + 2B rightarrow C + D Experimentally Determined Rate Law: rate = K[A][B]^2 Two-Step Mechanism: Step 1: Step 2:
5. The reaction 2NO+ Cl2 → 2NOCI is thought to occur in two steps, as shown by the following proposed mechanism: O NO + Cl2 NOCI (fast, at equilibrium) (i) NO + NOCI, → 2NOCI (slow) What rate law does this mechanism predict? Select the best choice by circling it. a. rate = ** [NO]?[NOCI] rate = *, [NO]2 C. rate = [NOCL] d. rate = kek [NO](C1,12 rate = [NO] f. rate = kaka [NO]+[C12] g. rate = kak2...
The rate equation for the reaction 2NO(g) + Br_2(g) rightgarrow 2NOBr(g) was determined experimentally to be: Rate = k[NO]^2 [Br_2] Five possible mechanisms have been proposed (i)-(v). Determine the rate equation for each mechanism below and then decide with reasons, (based on the information given) which mechanism is the most likely. (i) 2NO (g) + Br_2 (g) rightarrow 2NOBr (g) (ii)NO (g) + Br_2 rightwardsharpoonoverleftwardsharpoon NOBr_2 (g) NOBr_2 (g) + NO (g) rightarrow 2NOBr (g) (iii) Br_2 rightwardsharpoonoverleftwardsharpoon Br +...
3.(12pts) The reaction Cl(aq) + HS(a) determined DRL S)+(aq) +2 Cl(aq) has the experimentally rate k[Cl2][H2S] Which of the following mechanisms is(are) consistent with the experimental results. Mech I Mech 11, Mech III Cl2 +H2S >H CI CI+HS (slow) CI+ + HS. …>H+ + Cl. + S H2S = HS. + H+ HSCl2 2CI +S+H (fast) (fast equil) (slow) H2S HS+H (fast equil) (fast equil) (slow) 4. (10 pts) Write the equilibrium constant Ke expression for the following 4 KO:(s)...
Please answer each part with work shown. Thank you.
6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +NON2+0 (fast) O+H2-> H2O (fast) 2 NO-N202 (fast equilibrium) H2-N202-H20+ N3O (slow) H2+N20-H2O+N2 (fast) H2 + 2 NO- H2O+N2O (slow) N20+ H2N2+ H2O (fast) a) What is the overall reaction that each proposed mechanism supports? b) Calculate the ΔΗ'm for the overall reaction. c) For each mechanism, draw an energy...
13 Interpreting Mechanisms S20(1) - Protected View - Saved - Search References Mailings Review View ain viruses. Unless you need to edit, it's safe stay in Prolus i ew. Enable Editing Student Name: #13 Interpreting Mechanisms 1. Consider the following mechanism: Step 1 Brz Step 2 Br + H2 Step 3 H2Br Br - fast 2Br H2Br 2HBO fast slow a. What is the overall equation? b. Identify the intermediate(s) if any. c. What is the molecularity and the rate...
step by step
Rates of Non-elementary reactions Class Activity Consider the following mechanism: 2NO N202 k-1 NzOz + C12-2+2 NOCI a. What is the net reaction? b. Which of the above species is an intermediate? Why? c. Find the rate of the overall reaction using the steady-state approximation. d. Repeat part (c) using the rate-determining step method, assuming the first-step is fast and at equilibrium and the second step is slow. 2NO N,02 (ast,at equilibrium) k-1 N202 + Cl2-22 NOCI...
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