Question

The rate equation for the reaction 2NO(g) + Br2(g) → 2NOBr(g) was determined experimentally to be: (b) Rate = k[NO]2[Br] Five possible mechanisms have been proposed (i) - (v) Determine the rate equation for each mechanism below and then decide with reasons, (based on the information given) which mechanism is the most likely. (i) 2NO(g) + Br2(g) →2NOBr (g) NO (g)+ Br2 NOBr2(g)+NO(g) (ii) NOBT2(g) -) 2NOBr (g) (iii) Br2= Br + Br + NO (g) → NOBr (g) Br + NO (g) → NOBr (g) NO (g) + Br2(g) Br (iv) → NBr2(g) → 2NOBr (g) fast slow NBr2 (g) + O2 (g) →N2O2 (g) slow fast (v) 2NO (g) N2O2(g) + Br2(g) → 2NOBr (g)

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Answer #1

K-t untals Huu NoBY ї) an inter medida and thi in ( K-1 K-1 K-1

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