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A 1H NMR signal is observed at 123.0 Hz (downfield of TMS) on a 135-MHz instrument.a)...

A 1H NMR signal is observed at 123.0 Hz (downfield of TMS) on a 135-MHz instrument.a) What is the observed chemical shift in parts per million (ppm)?b) What is the chemical shift, in parts per million (ppm), if the sample is analyzed with a 400.0-MHz instrument?c) Where will the proton signal appear, in hertz, if the sample is analyzed with a 400.0-MHz instrument?

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Answer #1

(a) Chenicalshift (s) in Ppr = Distance from the peak (H2) y Instrument frequency CHH2) = 183 HZ 135 MHz = 3.5 PPM b cheppica

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