You placed 6.35 g of a mixture containing unknown amounts of BaO(s) and MgO(s) in a 3.50-L flask containing CO₂(g) at 30.0°C and 750. torr. After the reaction to form BaCO₃(s) and MgCO₃(s) was completed, the pressure of CO₂(g) remaining was 135 torr. Calculate the mass of BaO(s) in the mixture.
Initial number of moles of carbon dioxide is calculated by using Ideal gas equation.
PV = nRT
Given that Carbon dioxide is present in 3.5 L flask and 30°C and 750 torr.
Number of moles of Carbon dioxide = PV/RT
= 0.986 atm*3.5 L/(0.0821 lit atm/ K-mol) * 303 K
= 0.139 moles
Pressure of carbon dioxide after completion of the reaction is 135 torr.
Number of moles of carbon dioxide =
0.178 atm*3.5 L/(0.0821 lit atm/ K-mol) * 303 K
= 0.0249 moles
Number of moles of carbon dioxide reacted = 0.139 - 0.0249
= 0.114 moles
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