Homework Answers
all are alkene addition reactions and the possible
products are as follows
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Indicate stereochemistry of product(s) where appropriate. H-Br Bra CH2Cl2 1. BHz/THF 2.HO.H202.H20 H-Br НО, BI2 mm...
Indicate stereochemistry of product(s) where appropriate. H-Br Bra CH2Cl2 1. BHz/THF 2.HO.H202.H20 H-Br НО, BI2 mm...
Indicate stereochemistry of product(s) where appropriate. H-Br Bra CH2Cl2 1. BHz/THF 2.HO.H202.H20 H-Br НО, BI2 mm Н,0 13 14 Li Be
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. (i) -COH На (i)...
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. (i) -COH На (i) Pd/C OsO4 NaHSO3, H20 н СHC1, КОН (iv) i) ВН, THF CECH in) H,О, NaOH Li, NH3 (liquid) (vi) XX H/H20 (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. он BH3, THF i)H202 NaOH он )Hg(OAc)2 H20 i)NaBH (iii CH O i) Zn/H +
Predict the product(s), both major and minor, of the following reactions. Indicate stereochemistry where appropriate. КОНЕТОН...
Predict the product(s), both major and minor, of the following
reactions. Indicate stereochemistry where appropriate.
КОНЕТОН OTs Ph н н а. Ph b. THF OMs NaOCH(CH3)2 с. Н НОСHCH)2
OH r. Он reagent(s) Br OEt S. reagent(s) Br Он K2Cr2O7 (excess) H2SO4, H20 Он но...
OH r. Он reagent(s) Br OEt S. reagent(s) Br Он K2Cr2O7 (excess) H2SO4, H20 Он но 1. PhLi, Et O 2. HCI, H2O 3. SOCI2, EtN 4. NaOAc u. н 1. Mg (1 eq), Et2O V. Br 2. (1 eq) -сно 3. HCI, Н,О W. 1. NaBH,, MeOН, 0° С 2. PBra THF 3. LIAID4, THF 4. HCI, H20
(24 pts) 3. Predict the product(s) for each reaction. Indicate stereochemistry if known. If more than...
(24 pts) 3. Predict the product(s) for each reaction. Indicate stereochemistry if known. If more than one product is predicted, circle the one you think would be major. If there is no reaction expected, then indicate NR. а. HaCl.. Br NaCN THF b. Н—Br ether ОН с. CH3 КОН Br THF d. НОСН heat е. PBr3 ОН ether f. ОН NaSCH3 Hо g. cat Br H2SO4 heat ОН h Br H но heat Br
Don't understand how you get these particular ones. RCO3H y 60,4 ignore stereochemistry NH PCC/CH2Cl2 H...
Don't understand how you get these particular ones.
RCO3H y 60,4 ignore stereochemistry NH PCC/CH2Cl2 H pH = 4 1) Mg/Et20 2) HH HOOH H30+ 3) H20+ ignore stereochemistry 1) 03 Она -- 2) Н,0 Конноллон но* Осоон зууны, COOH 1) Br2, PBrz 2) Н,0 но - ден. 1) H,Crод он —2) А „Соонд HOOC 1) V PPh3 2) Os04 3) NaHSO3 4) I /HCI 1) NaOH 2) PCC(excess)/CH2Cl2 3) pH = 4 MNH NH2 h Br 1) Mg/Et,o 2)...
Predict the product(s), both major and minor, of the following reactions. Indicate stereochemistry where appropriate. Br....
Predict the product(s), both major and minor, of the following
reactions. Indicate stereochemistry where appropriate.
Br. H Nang g DMF OH H2PO4 OMS KOC(CH3)3 HOC(CH3)3
predict the major organic product(s) of the following reactions. Indicate stereochemistry ps.) Predict the major organic...
predict the major organic product(s) of the following reactions.
Indicate stereochemistry
ps.) Predict the major organic product or products of the following reactions Indicate stereochemistry of product(s) where appropriate. CHCI 1. BH,THE 2. HÔ , HO, HẠO H-Br H₂O₂ Brz НО
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br...
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
1. [6 points] Predict the major product/s of the following reactions. Indicate stereochemistry using dashed and...
1. [6 points] Predict the major product/s of the following reactions. Indicate stereochemistry using dashed and wedged bonds where appropriate 1. BH2 and THF 2. NaOH and H202 H30 H20 CI H20
Indicate stereochemistry of product(s) where appropriate. H-Br Bra CH2Cl2 1. BHz/THF 2.HO.H202.H20 H-Br НО, BI2 mm Н,0 13 14 Li Be
Predict the major product(s) of the following reactions. Show stereochemistry where appropriate. (i) -COH На (i) Pd/C OsO4 NaHSO3, H20 н СHC1, КОН (iv) i) ВН, THF CECH in) H,О, NaOH Li, NH3 (liquid) (vi) XX H/H20 (vii) Two Markovnikov products Draw the structure of alkene for each of the following reactions. он BH3, THF i)H202 NaOH он )Hg(OAc)2 H20 i)NaBH (iii CH O i) Zn/H +
Predict the product(s), both major and minor, of the following
reactions. Indicate stereochemistry where appropriate.
КОНЕТОН OTs Ph н н а. Ph b. THF OMs NaOCH(CH3)2 с. Н НОСHCH)2
OH r. Он reagent(s) Br OEt S. reagent(s) Br Он K2Cr2O7 (excess) H2SO4, H20 Он но 1. PhLi, Et O 2. HCI, H2O 3. SOCI2, EtN 4. NaOAc u. н 1. Mg (1 eq), Et2O V. Br 2. (1 eq) -сно 3. HCI, Н,О W. 1. NaBH,, MeOН, 0° С 2. PBra THF 3. LIAID4, THF 4. HCI, H20
(24 pts) 3. Predict the product(s) for each reaction. Indicate stereochemistry if known. If more than one product is predicted, circle the one you think would be major. If there is no reaction expected, then indicate NR. а. HaCl.. Br NaCN THF b. Н—Br ether ОН с. CH3 КОН Br THF d. НОСН heat е. PBr3 ОН ether f. ОН NaSCH3 Hо g. cat Br H2SO4 heat ОН h Br H но heat Br
Don't understand how you get these particular ones.
RCO3H y 60,4 ignore stereochemistry NH PCC/CH2Cl2 H pH = 4 1) Mg/Et20 2) HH HOOH H30+ 3) H20+ ignore stereochemistry 1) 03 Она -- 2) Н,0 Конноллон но* Осоон зууны, COOH 1) Br2, PBrz 2) Н,0 но - ден. 1) H,Crод он —2) А „Соонд HOOC 1) V PPh3 2) Os04 3) NaHSO3 4) I /HCI 1) NaOH 2) PCC(excess)/CH2Cl2 3) pH = 4 MNH NH2 h Br 1) Mg/Et,o 2)...
Predict the product(s), both major and minor, of the following
reactions. Indicate stereochemistry where appropriate.
Br. H Nang g DMF OH H2PO4 OMS KOC(CH3)3 HOC(CH3)3
predict the major organic product(s) of the following reactions.
Indicate stereochemistry
ps.) Predict the major organic product or products of the following reactions Indicate stereochemistry of product(s) where appropriate. CHCI 1. BH,THE 2. HÔ , HO, HẠO H-Br H₂O₂ Brz НО
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary (10 points total) Br HBr CH2CI Br2 HBr Но ROOR CH,OH Н,о н* Н,о° 1) Hg(O,CCF3)2 CH,OH 1) BН, THF 2) H,О, NaOH, Нао 2) NaBH, NaOH 1) Hg(OAc) Н0, THF/ Hа Pd/C 2) NaBH, NaOH
1. [6 points] Predict the major product/s of the following reactions. Indicate stereochemistry using dashed and wedged bonds where appropriate 1. BH2 and THF 2. NaOH and H202 H30 H20 CI H20
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