1) The following three schemes are missing reagents or products. Each missing reagent is 2 pts,...
Any help is appreciated!! 1) The following three schemes are missing reagents or products. Each missing reagent is 2 pts, each missing product is 3 pts. Do not add any reagents if something is already specified. Each scheme is independent. mCPBA DMP HN 2) Draw the mechanism of the acyl substitution reaction shown below. (8 pts)
Fill in the missing products or reagents (above blank arrows) for the following reaction schemes. No charged species should be drawn anywhere in this assignment. Acidic workup steps are assumed and are NOT explicitly included. Scheme 1: 10 pts EC- H2 KMnO4 Lindlar OH O ملتين NAOMe MeOH Scheme 2:12 pts 1) LDA H2O MgBr 2) O H2SO4 NaH Br LINHA mCPBA
2. Provide the missing products/reagents for the following reactions (2 pts each, 12 pts) 3. Protecting groups are important in Organic synthesis. We have seen 3 different protecting groups so far. Pick one and show how it is added, how it is removed, and what unwanted reactivity of the starting functional group it avoids. 4 pts) It is actually possible to oxidize ketones to esters using a reaction we have not talked about the Baeyer Villager reaction - which uses...
For the following reaction: a) Complete the reaction schemes by drawing the appropriate reagents and/or products in the spaces designated. b) Provide the generic name of Reagent Y. c) Provide the detailed mechanism for each step of the reaction.
Propose the missing products /reagents 1. (35 pts) Propose any 10 out of 18 missing reagents/products (if any). Mark them with an aster (only 10 will be graded). (3 pts for ench correct answer, 1 pts for each incorrect answer, final pt adjusted to 35 pts maximum): Ph 2 steps H,Cro Phot он 1) ( 17. PhCI Phoн HgSO4 но 15 16. PhH2) PCC Phcн,
13. (15) For each a For each of the following reactions, fill in the missing reagents from the list provided for Wormation of the product shown. Sequential steps, if necessary. should be numbered. Reagents can be used more than once. Reagent List: H2 C H2O2 = NaH PBT OCI NaBH. Pd/C NaOH BH2O HO HgCl2 Pd/Caco, Br2 HBr H2O (HOAC) (MCPBA) (pyridine) (Msch) por -Cl menos de plaqueta don -он i н он
this is organic chemistry, please help with both if you can. 1. Give the missing reagents, reactants or products for each of the following reactions. Answer the question associated with part b; if stereochemistry is required, you need to show dashes and wedges on the chiral centers only. (3 pts) a. Hyllindlar H2O/H HI b. give one stereoisomer OH HB/ROOR How many possible stereoisomers are produced? E1 give one stereoisomer PCC Excess H, H CHC12 d. OH KMnO4 HO H...
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH3)2 (E2) 1. BH3 2. H2O2, NaOH, H2O PCC HBr/ROOR how many stereoisomers? PCC ad Excess H, H CH2Cl2 OT_HBr SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction ОН PCC CH2Cl2 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH PCC CH2Cl2 HI (SN1)
Please explain in details 3. Each reaction below is missing the substrate, reagent(s), or product(s), as indicated by the box. Write the missing substance(s) in the space provided to the right. Do not show any mechanisms or intermediates!!! Be sure to show stereochemistry where appropriate. If the products are missing, you must show all possible major products. If the s are missing, you must determine the number and order of reagents used. If the substrate is missing you only need...
1. Give the missing reagents, reactants or products for each of the following reactions. KOC(CH . (E2) 1.BH 2. H2O NaOH, HÔ PCC HB/ROOR how many stereoisomers? how many stereoisomers? PCC Excess H2O H CH2C12 HB Nal SN2 give one stereoisomer SN2 NaCN ACN (solvent) KMnO4 HO H2SO mCPBA NaOEt (E2) H2SO4 (cat) don't worry about this reaction OH OH KMnO4 H2SO4 NaOEt (E2) mCPBA H2SO4 (cat) don't worry about this reaction OH Рcc CH2C12 HI (SN1)