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5. Explain how the following changes will influence the rate of the reaction of 2-bromo-2- methylbutane...
answer all 1. In each of the following, indicate which S2 reaction will occur faster. Explain...
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1. In each of the following, indicate which S2 reaction will occur faster. Explain your reasoning. a. 1-bromo-2,2-dimethylpropane or 1-bromo-3-methylbutane with Nal in DMSO. b. 1-iodopentane with NaN, in ethanol or NaSCH, in ethanol, c. Reaction of isobutyl iodide with NaBr in acetone or in ethanol. 2. In each of the following, indicate which S, 1 reaction will occur faster. Explain your reasoning. a. Reaction of I-chloro-1-methylcyclohexane or 1-chloro-2-methylcyclohexane in aqueous ethanol. b. Reaction of 2-chloropentane or 3-bromohexane...
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate...
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate the mechanism (S, S,2, El, E2). 80°C a 2-chloro-2-methylbutane NaOH Н.о b. (R)-2-chloropentane Nac c-H DMSO с1 (снс. Cн, CH,ОН d. trans-1-chloro-3-methylcyclohexane+ NaOC(CH) e. 2-chloro-3-phenylbutane Н.о f. trans-1-bromo-3-methyleyclopentane Nal acetone NaOCH THон g 2-chloro-2-methylbutane EIOH h R-3-bromo-2-methylpentane . trans-1-bromo-2-isopropyleyclohexane CHCOK NaSH Н,о j. 1-bromopropaе NaOCH снон CH коссH). I-bromobutane m. cis-1-chloro-3-methyleyclobutane Nal DMSO сHсH,он n. (R)-2-iodo-2-phenylethane NaOH o. 1-iodobutane p. 2-bromo-3-methylbutane KOC(CH). но (S)-3-chlorocyclopentene...
Arrange the following chloroalkanes in order of increasing reactivity towards a S_N1 reaction: 1-chloro-2-methylbutane, 1-chloro-3-methylbutane, 2-chloro-2-methylbutane,...
Arrange the following chloroalkanes in order of increasing reactivity towards a S_N1 reaction: 1-chloro-2-methylbutane, 1-chloro-3-methylbutane, 2-chloro-2-methylbutane, 1-chloropentane (A complete answer will provide a bond line drawing of each of the compounds listed) For the same compounds found in question 1, list them in order of increasing reactivity towards an S_N2 reaction (list them as structures as well) Provide a bond line drawing of the product for the following reactions: (answer on back) a. (2S)-2-bromobutane + NaCN in acetone b. (3R)-3-iodo-1...
3) Complete the reactions to show the multi-step syntheses of each product from (R)-2 bromo-3-methylbutane. Reaction...
3) Complete the reactions to show the multi-step syntheses of each product from (R)-2 bromo-3-methylbutane. Reaction conditions go in boxes above arrows (1 reaction/box) Complete the template molecules provided to show each step of the synthesis. [20] Hint- This question involves addition, elimination, substitution and alcohol chemistry Br (R)-2-bromo-3-methylbutane 3-methylbutan-1-ol (R)-2-bromo-3-methylbutane (R)-3-bromo-2 methylbutan-2-ol (R)-2-bromo-3-methylbutane (1-chloro-2-methylbutane (R)-2-bromo-3-methylbutane CN ()-1-cyano-3-methylbutan-1-ol
1. Show the conditions for and products of an El and E2 reaction with a. cis...
1. Show the conditions for and products of an El and E2 reaction with a. cis and trans iso ne. mers of 1-chloro-2-ethylcyclohexa b. (3R,4R)-4-bromo-3-methylpent-1-ene and it's diastereomer. 2. Which stereoisomer reacts more quickly in E2 reaction - 1R,3R-1-bromo-3- methylcyclohexane, 1S,3S-1-bromo-3-methylcyclohexane, 1R,2S-1-bromo-3- romo-5-methylcyclonexane, methylcyclhexane, 1S,2R-1-bromo-3-methylchyclohexane?
13a. Draw the electron pushing using arrows for 2-Bromo-2-methylbutane reacting with methanol. Consider both substitution and...
13a. Draw the electron pushing using arrows for 2-Bromo-2-methylbutane reacting with methanol. Consider both substitution and elimination mechanisms. Show the structure of products. 13b. Does cis- or trans- bromo-4-tert-butylcyclohexane react faster in an E2 reaction? Explain.
Predict the substitution product(s) for each of the following reactions and mechanisms by which they are...
Predict the substitution product(s) for each of the following reactions and mechanisms by which they are formed. If no reaction is expected, write no (a) (R)-2-bromobutane with sodium iodide in acetone (b) (R)-3-bromo-3-methylhexane with H20 (c) trans-1-bromo-2-ethylcyclopentane with potassium ethoxide in ethanol (d) trans-1-bromo-3-methylcyclopentane with Nal in acetone 5. For the following set of compounds, predict the order of reactivity with sodium iodide in acetone solution (list them in increasing order of reactivity). C. D. 2-bromobutane 1-chlorobutane 2-chloro-3-methylbutane 2-bromo-2-methylpropane 1-bromobutane...
Organic Chemistry please help asap 70. What nucleophiles wou cleophiles would form the following compounds as...
Organic Chemistry please help asap
70. What nucleophiles wou cleophiles would form the following compounds as a result of reacting with l-iodobutane? OH SH 11. Draw (R)-2-bromopentane + CHO b. (R)-3-bromo-3-methylheptane + CH,OH c. benzyl chloride + CH CH OH te tollowing reactions: if the products can exist as stereoisomers, show what striscmers are obtained d. allyl chloride + CHOH e. 1-bromo-2-butene + CHO 1. l-bromo-2-butene + CH OH the products obtained from the solvolysis of each of the following...
Will a carbocation rearrangement occurs in the reaction of 2-bromo-3-methylbutane with methanol. Please explain why or...
Will a carbocation rearrangement occurs in the reaction of 2-bromo-3-methylbutane with methanol. Please explain why or why not
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1. In each of the following, indicate which S2 reaction will occur faster. Explain your reasoning. a. 1-bromo-2,2-dimethylpropane or 1-bromo-3-methylbutane with Nal in DMSO. b. 1-iodopentane with NaN, in ethanol or NaSCH, in ethanol, c. Reaction of isobutyl iodide with NaBr in acetone or in ethanol. 2. In each of the following, indicate which S, 1 reaction will occur faster. Explain your reasoning. a. Reaction of I-chloro-1-methylcyclohexane or 1-chloro-2-methylcyclohexane in aqueous ethanol. b. Reaction of 2-chloropentane or 3-bromohexane...
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate the mechanism (S, S,2, El, E2). 80°C a 2-chloro-2-methylbutane NaOH Н.о b. (R)-2-chloropentane Nac c-H DMSO с1 (снс. Cн, CH,ОН d. trans-1-chloro-3-methylcyclohexane+ NaOC(CH) e. 2-chloro-3-phenylbutane Н.о f. trans-1-bromo-3-methyleyclopentane Nal acetone NaOCH THон g 2-chloro-2-methylbutane EIOH h R-3-bromo-2-methylpentane . trans-1-bromo-2-isopropyleyclohexane CHCOK NaSH Н,о j. 1-bromopropaе NaOCH снон CH коссH). I-bromobutane m. cis-1-chloro-3-methyleyclobutane Nal DMSO сHсH,он n. (R)-2-iodo-2-phenylethane NaOH o. 1-iodobutane p. 2-bromo-3-methylbutane KOC(CH). но (S)-3-chlorocyclopentene...
Arrange the following chloroalkanes in order of increasing reactivity towards a S_N1 reaction: 1-chloro-2-methylbutane, 1-chloro-3-methylbutane, 2-chloro-2-methylbutane, 1-chloropentane (A complete answer will provide a bond line drawing of each of the compounds listed) For the same compounds found in question 1, list them in order of increasing reactivity towards an S_N2 reaction (list them as structures as well) Provide a bond line drawing of the product for the following reactions: (answer on back) a. (2S)-2-bromobutane + NaCN in acetone b. (3R)-3-iodo-1...
3) Complete the reactions to show the multi-step syntheses of each product from (R)-2 bromo-3-methylbutane. Reaction conditions go in boxes above arrows (1 reaction/box) Complete the template molecules provided to show each step of the synthesis. [20] Hint- This question involves addition, elimination, substitution and alcohol chemistry Br (R)-2-bromo-3-methylbutane 3-methylbutan-1-ol (R)-2-bromo-3-methylbutane (R)-3-bromo-2 methylbutan-2-ol (R)-2-bromo-3-methylbutane (1-chloro-2-methylbutane (R)-2-bromo-3-methylbutane CN ()-1-cyano-3-methylbutan-1-ol
1. Show the conditions for and products of an El and E2 reaction with a. cis and trans iso ne. mers of 1-chloro-2-ethylcyclohexa b. (3R,4R)-4-bromo-3-methylpent-1-ene and it's diastereomer. 2. Which stereoisomer reacts more quickly in E2 reaction - 1R,3R-1-bromo-3- methylcyclohexane, 1S,3S-1-bromo-3-methylcyclohexane, 1R,2S-1-bromo-3- romo-5-methylcyclonexane, methylcyclhexane, 1S,2R-1-bromo-3-methylchyclohexane?
Predict the substitution product(s) for each of the following reactions and mechanisms by which they are formed. If no reaction is expected, write no (a) (R)-2-bromobutane with sodium iodide in acetone (b) (R)-3-bromo-3-methylhexane with H20 (c) trans-1-bromo-2-ethylcyclopentane with potassium ethoxide in ethanol (d) trans-1-bromo-3-methylcyclopentane with Nal in acetone 5. For the following set of compounds, predict the order of reactivity with sodium iodide in acetone solution (list them in increasing order of reactivity). C. D. 2-bromobutane 1-chlorobutane 2-chloro-3-methylbutane 2-bromo-2-methylpropane 1-bromobutane...
Organic Chemistry please help asap
70. What nucleophiles wou cleophiles would form the following compounds as a result of reacting with l-iodobutane? OH SH 11. Draw (R)-2-bromopentane + CHO b. (R)-3-bromo-3-methylheptane + CH,OH c. benzyl chloride + CH CH OH te tollowing reactions: if the products can exist as stereoisomers, show what striscmers are obtained d. allyl chloride + CHOH e. 1-bromo-2-butene + CHO 1. l-bromo-2-butene + CH OH the products obtained from the solvolysis of each of the following...
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