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Organic Chemistry please help asap
70. What nucleophiles wou cleophiles would form the following compounds as...
need help with these practice problems please :) if can help with all would greatly appreciate....
need help with these practice problems please :) if can help with
all would greatly appreciate.
A. Predict how reaction conditions (substrate, nucleophile, leaving group, solvent) effect the rate of Swi and S2 reactions. Circle the faster substitution reaction among the following pairs. If the rate is not affected, circle both OH OH in acetone ta NaBr DMSO in H2O NaBr CH, OH V CI Br- na ro ChOH CHCI Bra CHCI ? © CN acetone CI- in H20 in...
12-14 confused helpp 12. What is the major organic product obtained from the following reaction? -сн,...
12-14 confused helpp
12. What is the major organic product obtained from the following reaction? -сн, Нс- ОН pyridine CH3 1 a. b. 2 3 с. d. 4 13. What is the major organic product obtained from the following reaction? 1 H-SO он SH 4 3 1 a. b. 3 с. 4 d. What is the major organic product obtained from the following reaction? 14. CrO3 OH H2SO, H2O 1-butene, CH2CH CH-CH butanal, CH,CH,CH,CHO butanone, CH:CH-COCH butanoic acid, CH CH-CH,COOH...
give the iupac names for the following compounds Fall 2009 Fall 2009 CHE212 Organic Chemistry I...
give the iupac names for the following compounds
Fall 2009 Fall 2009 CHE212 Organic Chemistry I Name Hour Exam Ch 4, 5, 6 & 7 100 Points 1.(10) Give the IUPAC names for the following compounds: Nov. 20, 2009 (b) CH, (a) CH2CH2CH=CHCH2CH2CH2CH; 3-octene CH,CCH2CHCH2CH3 OH CH3 2.(10) Draw the structure of each of the following compounds: (a) 3-methyl-2-hexanol (b) cis-2,3-dibromo-2-butene
1. Draw structures for the following compounds: a) l-ethyl-2-methylcyclohexane b) 4-methyl hexanal c) N-N-dimethylpentanamide 2. What...
1. Draw structures for the following compounds: a) l-ethyl-2-methylcyclohexane b) 4-methyl hexanal c) N-N-dimethylpentanamide 2. What is the product of this bromination reaction? H2C-CH=CH-CH2-CH2-CH3 + Br2 3. What is the product of this oxidation reaction? OH H3C-CH-CH-CHg 10 Сн, 4. Consider the esterification reaction reaction below: H, SO H3C-CH2-CH2-CH2-C-OH + H2C-CH2-OH What organic compound is the reactant on the left? What organic compound is the reactant on the right? Draw the product of the reaction. What type of organic compound...
How are the following two compounds related? CH CH3 HO -H HO -Н Given the following...
How are the following two compounds related? CH CH3 HO -H HO -Н Given the following substitution reaction, what would the effect be of changing the solvent from CH3OH to (CH3)2S=0? H- OH H OH VS HO -H H -OH H -OH HO H + CH (CH2CH2-Br NaOH CH;(CH2), CH2-OH + NaBr CH OH CH2OH A. The reaction rate will increase. OB. There is no effect on the rate of the reaction, C. The reaction rate will decrease. Give the...
When the 2,7-dimethyl-4-octyne is treated with 2 moles (excess) HBr, the product(s) of the reaction is:...
When the 2,7-dimethyl-4-octyne is treated with 2 moles (excess) HBr, the product(s) of the reaction is: CH-CH-CH-CH-CH-CH-CH-CH, B. CH3-CH-CH CH -CH2-CH-CH-CH; C CH-CH-CH2-C-CH3-CH-CH-CH н D. A mixture of a and b would be produced. A mixture of a, b, and e would be produced OB 0 0 0 Which of the following is the correct structure for 4-sec-butyl-1-heptyne? D. none of these OD What is the major organic product obtained from the following reaction? OH M CH,CH-CH-CH2=CH- 3 OH •...
2. When (1R, 2R)-1-bromo-2-methylcyclohexane reacts with lithium methoxide in methanol, both substitution and elimination reactions occur...
2. When (1R, 2R)-1-bromo-2-methylcyclohexane reacts with lithium methoxide in methanol, both substitution and elimination reactions occur to produce three unique products. What are the structures of the three products produced by this reaction? sepenbare CHOLE сно CH3 3. When (R)-3-mesyl-3-ethyloctane reacts with potassium hydroxide in aqueous THF elimination occurs to produce three unique alkene products. What are the structures of the three products produced by this reaction? MsOCH.CH HOK THF/H20 4. When (S)-2-fluoro-2-iodobutane reacts with hydroxide ion in aqueous THF,...
please show all steps including each mechanism (arrows) and also if SN1 has any rearrangements of...
please show all steps including each mechanism (arrows) and
also if SN1 has any rearrangements of carbocation intermediate
through a hydride shift and/or methyl shift. DO NOT NEED
ELIMINATION. ONLY SUBSTITUTION.
Sy1/E1 versus S2/E2 Learning Checks Draw the major organic substitution and/or elimination products in the following reactions. If no reaction is possible, write “No Reaction". Substitution Product(s) Elimination Product(s) 2) 2) OH BrCH K* -Ot-Bu NaOCH н"Сн, сн,он нсн, Ph NaOCH Br H CH3OH CH NaOCH NaOH T.CH, I...
organic chemistry 1.1 pt) Which reagent would you use to effect the following transformation of a...
organic chemistry
1.1 pt) Which reagent would you use to effect the following transformation of a diol into a keto acid? ОН Reagent? CH,CHCH,CH,CH,OH - CH,CCH,CH,сон a) Jones(H2Cr2O7) b) Tollens c) mCPBA d) Collins(PCC) e) LiAlH4 2.(2 pts) Circle the TWO compounds that yield a stable Grignard reagent when treated with magnesium in ether. Br CHÚC HỌC=CH- CH,OH HN 3.(2 pts each) Reactions. Complete each reaction shown here. HỌC=CH- + HC=CH- -CH OH он 1. CH CH MgBrCH,CH,CH=CHCCH2CH3 2.H2O Сн,...
organic chemistry lab help 2-4 please 2. What key IR and NMR absorptions would allow you...
organic chemistry lab help 2-4 please
2. What key IR and NMR absorptions would allow you to determine that the products from the reactions above have been successfully synthesized? Ignore absorptions also found in the reactant 3. NaBH, usually reacts slowly or not at all with esters. Therefore, LiAlH, is often needed to reduce esters. Why do you think LiAlH, is more reactive than NaBH. (Hint: Compare the electronegativity of H versus Al or B). 93 4. Draw the mechanism...
need help with these practice problems please :) if can help with
all would greatly appreciate.
A. Predict how reaction conditions (substrate, nucleophile, leaving group, solvent) effect the rate of Swi and S2 reactions. Circle the faster substitution reaction among the following pairs. If the rate is not affected, circle both OH OH in acetone ta NaBr DMSO in H2O NaBr CH, OH V CI Br- na ro ChOH CHCI Bra CHCI ? © CN acetone CI- in H20 in...
12-14 confused helpp
12. What is the major organic product obtained from the following reaction? -сн, Нс- ОН pyridine CH3 1 a. b. 2 3 с. d. 4 13. What is the major organic product obtained from the following reaction? 1 H-SO он SH 4 3 1 a. b. 3 с. 4 d. What is the major organic product obtained from the following reaction? 14. CrO3 OH H2SO, H2O 1-butene, CH2CH CH-CH butanal, CH,CH,CH,CHO butanone, CH:CH-COCH butanoic acid, CH CH-CH,COOH...
give the iupac names for the following compounds
Fall 2009 Fall 2009 CHE212 Organic Chemistry I Name Hour Exam Ch 4, 5, 6 & 7 100 Points 1.(10) Give the IUPAC names for the following compounds: Nov. 20, 2009 (b) CH, (a) CH2CH2CH=CHCH2CH2CH2CH; 3-octene CH,CCH2CHCH2CH3 OH CH3 2.(10) Draw the structure of each of the following compounds: (a) 3-methyl-2-hexanol (b) cis-2,3-dibromo-2-butene
1. Draw structures for the following compounds: a) l-ethyl-2-methylcyclohexane b) 4-methyl hexanal c) N-N-dimethylpentanamide 2. What is the product of this bromination reaction? H2C-CH=CH-CH2-CH2-CH3 + Br2 3. What is the product of this oxidation reaction? OH H3C-CH-CH-CHg 10 Сн, 4. Consider the esterification reaction reaction below: H, SO H3C-CH2-CH2-CH2-C-OH + H2C-CH2-OH What organic compound is the reactant on the left? What organic compound is the reactant on the right? Draw the product of the reaction. What type of organic compound...
How are the following two compounds related? CH CH3 HO -H HO -Н Given the following substitution reaction, what would the effect be of changing the solvent from CH3OH to (CH3)2S=0? H- OH H OH VS HO -H H -OH H -OH HO H + CH (CH2CH2-Br NaOH CH;(CH2), CH2-OH + NaBr CH OH CH2OH A. The reaction rate will increase. OB. There is no effect on the rate of the reaction, C. The reaction rate will decrease. Give the...
When the 2,7-dimethyl-4-octyne is treated with 2 moles (excess) HBr, the product(s) of the reaction is: CH-CH-CH-CH-CH-CH-CH-CH, B. CH3-CH-CH CH -CH2-CH-CH-CH; C CH-CH-CH2-C-CH3-CH-CH-CH н D. A mixture of a and b would be produced. A mixture of a, b, and e would be produced OB 0 0 0 Which of the following is the correct structure for 4-sec-butyl-1-heptyne? D. none of these OD What is the major organic product obtained from the following reaction? OH M CH,CH-CH-CH2=CH- 3 OH •...
2. When (1R, 2R)-1-bromo-2-methylcyclohexane reacts with lithium methoxide in methanol, both substitution and elimination reactions occur to produce three unique products. What are the structures of the three products produced by this reaction? sepenbare CHOLE сно CH3 3. When (R)-3-mesyl-3-ethyloctane reacts with potassium hydroxide in aqueous THF elimination occurs to produce three unique alkene products. What are the structures of the three products produced by this reaction? MsOCH.CH HOK THF/H20 4. When (S)-2-fluoro-2-iodobutane reacts with hydroxide ion in aqueous THF,...
please show all steps including each mechanism (arrows) and
also if SN1 has any rearrangements of carbocation intermediate
through a hydride shift and/or methyl shift. DO NOT NEED
ELIMINATION. ONLY SUBSTITUTION.
Sy1/E1 versus S2/E2 Learning Checks Draw the major organic substitution and/or elimination products in the following reactions. If no reaction is possible, write “No Reaction". Substitution Product(s) Elimination Product(s) 2) 2) OH BrCH K* -Ot-Bu NaOCH н"Сн, сн,он нсн, Ph NaOCH Br H CH3OH CH NaOCH NaOH T.CH, I...
organic chemistry
1.1 pt) Which reagent would you use to effect the following transformation of a diol into a keto acid? ОН Reagent? CH,CHCH,CH,CH,OH - CH,CCH,CH,сон a) Jones(H2Cr2O7) b) Tollens c) mCPBA d) Collins(PCC) e) LiAlH4 2.(2 pts) Circle the TWO compounds that yield a stable Grignard reagent when treated with magnesium in ether. Br CHÚC HỌC=CH- CH,OH HN 3.(2 pts each) Reactions. Complete each reaction shown here. HỌC=CH- + HC=CH- -CH OH он 1. CH CH MgBrCH,CH,CH=CHCCH2CH3 2.H2O Сн,...
organic chemistry lab help 2-4 please
2. What key IR and NMR absorptions would allow you to determine that the products from the reactions above have been successfully synthesized? Ignore absorptions also found in the reactant 3. NaBH, usually reacts slowly or not at all with esters. Therefore, LiAlH, is often needed to reduce esters. Why do you think LiAlH, is more reactive than NaBH. (Hint: Compare the electronegativity of H versus Al or B). 93 4. Draw the mechanism...
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