Homework Answers
Due to angle strain the
cyclohexane exist as chair form to minimise strain. And the
reaction goes through sn1 process.
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please show all steps including each mechanism (arrows) and
also if SN1 has any rearrangements of...
In both examples below the reactants shown are combined to bring about a nucleophilic substitution (Spl,...
In both examples below the reactants shown are combined to bring about a nucleophilic substitution (Spl, S2) and/or elimination (E1, 12) reaction What is the major reaction that takes place in each case? CHCHCH,CH,Br NaOCH CH3OH SN2 E2 mixture of SN1 and E1 CH3 CH3 Сн, сансн, NaOCHE CH3OH S In both examples below the reactants shown are combined to bring about a nucleophilic substitution ( S What is the major reaction that takes place in each case? 2) and/or...
1. For each of the following reactions, write S if it is a substitution and E...
1. For each of the following reactions, write S if it is a substitution and E if it is an elimination. Also write R for all of those that are also rearrangements. CH-Oн heat NaOCHs + HBr HG OH Nal Hо acetone NaBr +HBr 2. Predict which reactions proceeded by an SN1, SN2, El or E2 mechanism: NaOCH CH +NaBr оснCH Носн,сн, 50° +NaCl Nal DMSO, 45 Br NaOCHa +NaBr +HOCH Носн, 100° но +HI acetone, 50 HSO +HO HO,...
1. for each of thenfollowing write S if it is substitue and E if it is elimination. also write R for those that are rear...
1.
for each of thenfollowing write S if it is substitue and E if it is
elimination. also write R for those that are rearrangement
2. predict which reactions proceed by SN1 SN2 E1 or E2
mechanism
10/2ery due MON Unit 3 HW#2 Chemistry 420 wo Name: 1. For each of the following reactions, write S if it is a substitution and E if it is an elimination. Also write R for all of those that are also rearrangements. +...
please indicate stereochemistry (20 marks) 1. Identify each of the following reactions as SN1, SN2, E1,...
please indicate stereochemistry
(20 marks) 1. Identify each of the following reactions as SN1, SN2, E1, or E2 and give the products formed in each case, and indicate the stereochemistry of the product if appropriate (mechanisms are not required). If no reaction would occur, indicate this with N.R. forno reaction" and give the reason for which you don't expect a product. a) E HEC-CH2-C...Br (CH3),C07 (CH3),COH CHE 70°C CH3 SN2 Morand SN2 H H₃C-CH2-c...Br. CN/DMSO in CH 25°C d) Br...
Please show the mechanism showing all possible substitution products. SN1 and SN2 only. Thank you. Determine...
Please show the mechanism showing all possible substitution
products. SN1 and SN2 only. Thank you.
Determine the major substitution product(s) for each of the following reactions. In addition, please state the mechanism that is employed in the formation of each product. (8 points) Br NaOCH 3 CH3OH H20 Heat
(a) For each substitution reaction, circle whether it proceeds by an Sy1 or S 2 mechanism....
(a) For each substitution reaction, circle whether it proceeds by an Sy1 or S 2 mechanism. (1.5 pts) (b) Draw the major organic product for each reaction. Be sure to indicate the appropriate stereochemistry, where necessary (1.5 pts) 2. NaCN S1 or S 2? Br THF SN1 or Sy2? но CH3 Hас, SN1 or SN2? CH,он
3. Shown below are a series of reactions. Predict the major product for each of them....
3. Shown below are a series of reactions. Predict the major product for each of them. Remember, you will need to first decide whether the reaction occurs by an SN2, SN1, E2, or E1 before you can determine what the product will be. Label each as SN2, SN1, E2, or E1. Hint: First decide whether S2/E2 or S1/E1 is favored, and then decide whether the reaction pathway goes by a substitution or elimination reaction. SN2 / SN1 E2/E1 Na DMSO,rt...
Write the major products and state whether it is SN1, SN2, E1, E2, E1cB, or none of the above. Show all stereochemistry...
Write the major products and state whether it is SN1, SN2, E1, E2,
E1cB, or none of the above. Show all stereochemistry.
Write the major product(s), and state whether it is Syl, Sy2, El, E2, ElcB, or none of the above. III. Clearly show all stereochemistry ОТ NH2 + CH, сH,он CH, н сH, sOcyBenzene н н. он H H H H сн,сн, NBS/CC оть CH Н.С H H PBr HO H Н- нн н.с H Cl CH CH3 (CH)o8...
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2,...
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. CH₂ Na O=CH₂ Hic Br 2 Draw complete mechanism with arrows for the SNI/E1 mechanism. Check for carbocation rearrangements CH3 + H2O 3. Which is the major product for the following reaction? Y CH + NaOH CH HO HO H₃ CH₂ H₃ HOCH CH₂ H₃ CHE CH₂ CH₂ CH3 CH 4. Name the following including the R/S, E/Z...
Write the major substitution product(s), and state whether sn1 or sn2. Clearly show all stereochemistry. Assume...
Write the major substitution product(s), and state whether sn1 or
sn2. Clearly show all stereochemistry. Assume stoichiometric amount
used (i.e., 1 equivalent) unless otherwise indicated.
Chem 204 Chanter 11 Exercises (Nusleophilic Substitution versus Elimination) Ο διοι Score: --- 10 Write the major substitution product(s), and state whether Ssl or S2. Clearly show all stereochemistry. Assume stoichiometric amount used (Le., I equiv) unless otherwise indicated. istyong hantuophile CHxBr + CH3- minan con IC-ö-CH3 H-C=C-CH,Br + - HO 1 .. 11 C20-0-0-0...
In both examples below the reactants shown are combined to bring about a nucleophilic substitution (Spl, S2) and/or elimination (E1, 12) reaction What is the major reaction that takes place in each case? CHCHCH,CH,Br NaOCH CH3OH SN2 E2 mixture of SN1 and E1 CH3 CH3 Сн, сансн, NaOCHE CH3OH S In both examples below the reactants shown are combined to bring about a nucleophilic substitution ( S What is the major reaction that takes place in each case? 2) and/or...
1. For each of the following reactions, write S if it is a substitution and E if it is an elimination. Also write R for all of those that are also rearrangements. CH-Oн heat NaOCHs + HBr HG OH Nal Hо acetone NaBr +HBr 2. Predict which reactions proceeded by an SN1, SN2, El or E2 mechanism: NaOCH CH +NaBr оснCH Носн,сн, 50° +NaCl Nal DMSO, 45 Br NaOCHa +NaBr +HOCH Носн, 100° но +HI acetone, 50 HSO +HO HO,...
1.
for each of thenfollowing write S if it is substitue and E if it is
elimination. also write R for those that are rearrangement
2. predict which reactions proceed by SN1 SN2 E1 or E2
mechanism
10/2ery due MON Unit 3 HW#2 Chemistry 420 wo Name: 1. For each of the following reactions, write S if it is a substitution and E if it is an elimination. Also write R for all of those that are also rearrangements. +...
please indicate stereochemistry
(20 marks) 1. Identify each of the following reactions as SN1, SN2, E1, or E2 and give the products formed in each case, and indicate the stereochemistry of the product if appropriate (mechanisms are not required). If no reaction would occur, indicate this with N.R. forno reaction" and give the reason for which you don't expect a product. a) E HEC-CH2-C...Br (CH3),C07 (CH3),COH CHE 70°C CH3 SN2 Morand SN2 H H₃C-CH2-c...Br. CN/DMSO in CH 25°C d) Br...
Please show the mechanism showing all possible substitution
products. SN1 and SN2 only. Thank you.
Determine the major substitution product(s) for each of the following reactions. In addition, please state the mechanism that is employed in the formation of each product. (8 points) Br NaOCH 3 CH3OH H20 Heat
(a) For each substitution reaction, circle whether it proceeds by an Sy1 or S 2 mechanism. (1.5 pts) (b) Draw the major organic product for each reaction. Be sure to indicate the appropriate stereochemistry, where necessary (1.5 pts) 2. NaCN S1 or S 2? Br THF SN1 or Sy2? но CH3 Hас, SN1 or SN2? CH,он
3. Shown below are a series of reactions. Predict the major product for each of them. Remember, you will need to first decide whether the reaction occurs by an SN2, SN1, E2, or E1 before you can determine what the product will be. Label each as SN2, SN1, E2, or E1. Hint: First decide whether S2/E2 or S1/E1 is favored, and then decide whether the reaction pathway goes by a substitution or elimination reaction. SN2 / SN1 E2/E1 Na DMSO,rt...
Write the major products and state whether it is SN1, SN2, E1, E2,
E1cB, or none of the above. Show all stereochemistry.
Write the major product(s), and state whether it is Syl, Sy2, El, E2, ElcB, or none of the above. III. Clearly show all stereochemistry ОТ NH2 + CH, сH,он CH, н сH, sOcyBenzene н н. он H H H H сн,сн, NBS/CC оть CH Н.С H H PBr HO H Н- нн н.с H Cl CH CH3 (CH)o8...
30. Late papers not accepted. Work Independently. 1. Predict the most likely reaction mechanism (SN1, SN2, E1, E2) and draw all products. CH₂ Na O=CH₂ Hic Br 2 Draw complete mechanism with arrows for the SNI/E1 mechanism. Check for carbocation rearrangements CH3 + H2O 3. Which is the major product for the following reaction? Y CH + NaOH CH HO HO H₃ CH₂ H₃ HOCH CH₂ H₃ CHE CH₂ CH₂ CH3 CH 4. Name the following including the R/S, E/Z...
Write the major substitution product(s), and state whether sn1 or
sn2. Clearly show all stereochemistry. Assume stoichiometric amount
used (i.e., 1 equivalent) unless otherwise indicated.
Chem 204 Chanter 11 Exercises (Nusleophilic Substitution versus Elimination) Ο διοι Score: --- 10 Write the major substitution product(s), and state whether Ssl or S2. Clearly show all stereochemistry. Assume stoichiometric amount used (Le., I equiv) unless otherwise indicated. istyong hantuophile CHxBr + CH3- minan con IC-ö-CH3 H-C=C-CH,Br + - HO 1 .. 11 C20-0-0-0...
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