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(a) For each substitution reaction, circle whether it proceeds by an Sy1 or S 2 mechanism....
please help with the middle mechanism 2. (a) For each substitution reaction, circle whether it proceeds...
please help with the middle mechanism
2. (a) For each substitution reaction, circle whether it proceeds by an S1 or Sn2 mechanism. (1.5 pts) (b) Draw the major organic product for each reaction. Be sure to indicate the appropriate stereochemistry, where necessary. (1.5 pts) - CN NaCN + Nabr Sw 1 of SN22 THE Sw1 or S2? Broken Co -CI + lon- HO CH3 OCH3
will you please check the ones i did also. 12. (I pt each) Each of the...
will you please check the ones i did also.
12. (I pt each) Each of the following reactions gives a substitution product. lIdentify the major product in each case and indicate whether the reaction is likely to proceed via a bimolecular (Su2) or a unimolecular (S1) mechanism. S1 OF 9,2 Br NaCN DMF SNI EtOH Aprotc Sy1 or SN2? он CH3 CHs он SN1 or SN2? electrophile nucleophile Br ONa DMF SN1 or Sy2? prot℃
Draw the major, neutral organic product obtained if: the reaction proceeds by the SN1 mechanism the reaction proceeds by the SN2 mechanism
Draw the major, neutral organic product obtained if: the reaction proceeds by the SN1 mechanism the reaction proceeds by the SN2 mechanism. Draw the major, neutral organic product for each substitution reaction below. (For this question, assume that each substitution reaction goes to completion. Disregard elimination.)
Draw the major, neutral organic product obtained if: the reaction proceeds by the SN1 mechanism the reaction proceeds by the SN2 mechanism. Draw the major, neutral organic product for each substitution reaction below. (For...
11. For each of the following reactions, predict whether Syl or Sy2 will be the primary...
11. For each of the following reactions, predict whether Syl or Sy2 will be the primary substitution mechanism. (Circle one) Br Nal in H2O - SN or SN2 CH,OH Sn1 or SN2 NaCN in DMSO Sn1 or S2 12. For the second reaction in question 11 (above), which do you think would react faster--the sec- ondary bromide or a secondary chloride (assuming the same reaction conditions)? (Circle one) Bromide Chloride Neither (rates are the same)
(24 pts) 3. Predict the product(s) for each reaction. Indicate stereochemistry if known. If more than...
(24 pts) 3. Predict the product(s) for each reaction. Indicate stereochemistry if known. If more than one product is predicted, circle the one you think would be major. If there is no reaction expected, then indicate NR. а. HaCl.. Br NaCN THF b. Н—Br ether ОН с. CH3 КОН Br THF d. НОСН heat е. PBr3 ОН ether f. ОН NaSCH3 Hо g. cat Br H2SO4 heat ОН h Br H но heat Br
Substitution Problems I. In each of the problems below, label the alkyl halide as primary, secondary, or tertiary. Labe...
Substitution Problems I. In each of the problems below, label the alkyl halide as primary, secondary, or tertiary. Label the nucleophile as strong or weak. Decide whether an SN2 or an Sy1 reaction occurs. After, show the mechanism and product or products. Indicate stereochemistry where appropriate. a. Reaction of 1-bromopropane and sodium methoxide in methanol CH3 Na CH,Oн Br b. Reaction of 2-bromopropane in ethanol CH3CH2OH Br c. Reaction of (R) 3-chloro-3-methyl heptane in acetic acid Ci Cн CH,COOH но...
please show all steps including each mechanism (arrows) and also if SN1 has any rearrangements of...
please show all steps including each mechanism (arrows) and
also if SN1 has any rearrangements of carbocation intermediate
through a hydride shift and/or methyl shift. DO NOT NEED
ELIMINATION. ONLY SUBSTITUTION.
Sy1/E1 versus S2/E2 Learning Checks Draw the major organic substitution and/or elimination products in the following reactions. If no reaction is possible, write “No Reaction". Substitution Product(s) Elimination Product(s) 2) 2) OH BrCH K* -Ot-Bu NaOCH н"Сн, сн,он нсн, Ph NaOCH Br H CH3OH CH NaOCH NaOH T.CH, I...
Predict the major product for the following reaction. Label whether the reaction will proceed through an...
Predict the major product for the following reaction. Label whether the reaction will proceed through an SN2, Sn1, E2, or E1 mechanism. SN2 / S1/E2/E1 сн. Br NaCN (1 mol) (1 mol) Predict the major product for the following reaction. Label whether the reaction will proceed through an SN2, SN1, E2, or E1 mechanism. SN27 SN1/E2/E1 NaOCH; Сн,он Draw the line structures of the reactants below and predict the product of their reaction. Label the reaction as SN1, SN2, E1,...
For the following reactions, determine the mechanism(s), Sy1, S2, E1 or E2. Show the mechanism(s) and...
For the following reactions, determine the mechanism(s), Sy1, S2, E1 or E2. Show the mechanism(s) and determine the product(s). Indicate major product if one is present. Include stereochemistry at stereogenic centers. KOC(CH3)a Br 12. CH3CH2OH 13. Cl он
For each of the following transformations: a) Show all Products formed State whether the mechanism favors...
For each of the following transformations: a) Show all Products formed State whether the mechanism favors SN1 or SN2 b) c) Show stereochemistry (*R/S) where applicable. d) Show an arrow that indicates which side of the reaction is favored, products or reactants. Br acetone + NaCN CH3CH2CH2NH2 ш HСІ он
please help with the middle mechanism
2. (a) For each substitution reaction, circle whether it proceeds by an S1 or Sn2 mechanism. (1.5 pts) (b) Draw the major organic product for each reaction. Be sure to indicate the appropriate stereochemistry, where necessary. (1.5 pts) - CN NaCN + Nabr Sw 1 of SN22 THE Sw1 or S2? Broken Co -CI + lon- HO CH3 OCH3
will you please check the ones i did also.
12. (I pt each) Each of the following reactions gives a substitution product. lIdentify the major product in each case and indicate whether the reaction is likely to proceed via a bimolecular (Su2) or a unimolecular (S1) mechanism. S1 OF 9,2 Br NaCN DMF SNI EtOH Aprotc Sy1 or SN2? он CH3 CHs он SN1 or SN2? electrophile nucleophile Br ONa DMF SN1 or Sy2? prot℃
Draw the major, neutral organic product obtained if: the reaction proceeds by the SN1 mechanism the reaction proceeds by the SN2 mechanism. Draw the major, neutral organic product for each substitution reaction below. (For this question, assume that each substitution reaction goes to completion. Disregard elimination.)
Draw the major, neutral organic product obtained if: the reaction proceeds by the SN1 mechanism the reaction proceeds by the SN2 mechanism. Draw the major, neutral organic product for each substitution reaction below. (For...
11. For each of the following reactions, predict whether Syl or Sy2 will be the primary substitution mechanism. (Circle one) Br Nal in H2O - SN or SN2 CH,OH Sn1 or SN2 NaCN in DMSO Sn1 or S2 12. For the second reaction in question 11 (above), which do you think would react faster--the sec- ondary bromide or a secondary chloride (assuming the same reaction conditions)? (Circle one) Bromide Chloride Neither (rates are the same)
(24 pts) 3. Predict the product(s) for each reaction. Indicate stereochemistry if known. If more than one product is predicted, circle the one you think would be major. If there is no reaction expected, then indicate NR. а. HaCl.. Br NaCN THF b. Н—Br ether ОН с. CH3 КОН Br THF d. НОСН heat е. PBr3 ОН ether f. ОН NaSCH3 Hо g. cat Br H2SO4 heat ОН h Br H но heat Br
Substitution Problems I. In each of the problems below, label the alkyl halide as primary, secondary, or tertiary. Label the nucleophile as strong or weak. Decide whether an SN2 or an Sy1 reaction occurs. After, show the mechanism and product or products. Indicate stereochemistry where appropriate. a. Reaction of 1-bromopropane and sodium methoxide in methanol CH3 Na CH,Oн Br b. Reaction of 2-bromopropane in ethanol CH3CH2OH Br c. Reaction of (R) 3-chloro-3-methyl heptane in acetic acid Ci Cн CH,COOH но...
please show all steps including each mechanism (arrows) and
also if SN1 has any rearrangements of carbocation intermediate
through a hydride shift and/or methyl shift. DO NOT NEED
ELIMINATION. ONLY SUBSTITUTION.
Sy1/E1 versus S2/E2 Learning Checks Draw the major organic substitution and/or elimination products in the following reactions. If no reaction is possible, write “No Reaction". Substitution Product(s) Elimination Product(s) 2) 2) OH BrCH K* -Ot-Bu NaOCH н"Сн, сн,он нсн, Ph NaOCH Br H CH3OH CH NaOCH NaOH T.CH, I...
Predict the major product for the following reaction. Label whether the reaction will proceed through an SN2, Sn1, E2, or E1 mechanism. SN2 / S1/E2/E1 сн. Br NaCN (1 mol) (1 mol) Predict the major product for the following reaction. Label whether the reaction will proceed through an SN2, SN1, E2, or E1 mechanism. SN27 SN1/E2/E1 NaOCH; Сн,он Draw the line structures of the reactants below and predict the product of their reaction. Label the reaction as SN1, SN2, E1,...
For the following reactions, determine the mechanism(s), Sy1, S2, E1 or E2. Show the mechanism(s) and determine the product(s). Indicate major product if one is present. Include stereochemistry at stereogenic centers. KOC(CH3)a Br 12. CH3CH2OH 13. Cl он
For each of the following transformations: a) Show all Products formed State whether the mechanism favors SN1 or SN2 b) c) Show stereochemistry (*R/S) where applicable. d) Show an arrow that indicates which side of the reaction is favored, products or reactants. Br acetone + NaCN CH3CH2CH2NH2 ш HСІ он
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