first calculate K from given data
[A]0 - [A] = K0t
[A0] = 0.710 M
30 % complete
70 % left
70 = (X / 0.710) x 100
0.70 = X / 0.710
X = 0.497
so [A ] = 0.497 M
0.710 - 0.497 = K x 72.2
0.213 = K x 72.2
K = 0.0029 min-1
now
for zero order
t1/2 = [A0] / 2 K0
t1/2 = 0.710 / 2 x 0.0029
t1/2 = 0.710 / 0.0058
t1/2 = 122 min
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