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6. For the following reactions tell whether they will react under Ss1 condition (EtOH, heat), Ss2 condition (Nal/acetone) or neither. Also indicate the product formed if any. (10 points) Mechanism Product (Sl or S2) Br TsO HaC ii. Br Br HC iv. H3C CH3 H3C OCH3
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2. Show the step by step mechanism to account for the following transformation. Also predict the major product formed. (20 points) CH3 OH conc. HBO CH₂ H₂CX Br CH₂ H3C CHE H₃C CH Swi condition Br L CH3 CH3 H₃C HC X X
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5. Predict the eliminations products A and B formed (E-1 mechanism) when 4,4-dimethylhexan- 3-ol is heated with concentrated phosphoric acid. Also, identify the rate determining step and the major product using Zaitsev's Rule? (Mechanism must be shown to receive full points) (20 pts) он conc. H3PO4 CH3 Products A and B нас E-1 condition HzC CH3 4,4-dimethylhexan-3-ol
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3. In the deuterium-labeled compound below predict the product(s) of the elimination reaction of the following elimination reaction and tell whether the alkene formed contains deuterium or not. (20 pts) HCCH; OH H2SO4(aq) heat н,с (ii) NaOCH.CH CH,CH,OH heat CH3 (iii) Write a detail mechanism for the formation of the product in question 3(i).
6&7 please
6. For the following reactions tell whether they will react under Secondition condition (Nal/acetone) or neither. Also indicate the product formed if any (10 points Mechanism Product (S.1 or 2) my НАС " H₂C CHO 7. Draw the major product expected in each reaction below. (10 pts) HAPO. HC CH3 heat OH CH3CH ONa нсін CH,CH OH 55°C B CH2CH3 KSH (1 mol equivalent) acetonitrile он acetonitrile
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7. Draw the major product expected in each reaction below. (10 pts) CH3 H3PO4 i. Hас. "CHз heat OH н CH3CH2ONA Hас н CH-CH-он ii CH2CH3 Br 55 °C н Насо. KSH (1 mol equivalent) ii. acetonitrile OTs Pон iv acetonitrile Но.
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1. Circle the mechanism (SN2, SN1, E2, or E1) responsible for the formation of each product in this reaction. If the product cannot be formed in the reaction, circle "not a product". (2 pts) CI CHE CH3 CHE CH3 осна SN2 SN1 E2 E1 S2 SN1 E2 E1 SN2 Sn1 E2 E1 SN2 SN1 E2 E1 not a product not a product not a product not a product 2. These reactions...
6. For the following reactions tell whether they will react under condition on condition (Nal/acetone) or neither. Also indicate the product formed if any (10 p m Mechanism Product (Swl or S.2) Hoc OCH 7. Draw the major product expected in each reaction below. (10 pts) 1 H HYPO heat CH OH нсун CH,CH,ONa CH,CH OH 55°C B CH.CH Нcos KSH Y (1 mol equivalent) acetonitrile H он acetonitrile Dr. Denton
6. For the following reactions tell whether they will react under sa condo non, hea), condition (Nal/acetone) or neither. Also indicate the product formed i (10 poi Mechanism Product (S.1 or 5.2) 7. Draw the major product expected in each reaction below. (10 pts) CH₂ H₃PO, H₂ CH₃ heat OH Hoogte CH,CH, ON CH,CH, OH 55°C il. B YCH CH3 HCO KSH (1 mol equivalent) acetonitrile OOH acetonitrile Dr. Denton
Please show the mechanism showing all possible substitution
products. SN1 and SN2 only. Thank you.
Determine the major substitution product(s) for each of the following reactions. In addition, please state the mechanism that is employed in the formation of each product. (8 points) Br NaOCH 3 CH3OH H20 Heat