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3. In the deuterium labeled compound below nredict the products of the elimination of the following elimination reaction and tell whether the alkene formed contains deutenum or not. (20 pts) HC CH3 OH H2SO4(aq) IH heat нстр (ii) NaOCH.CH CH,CH,OH heat CH3 (iii) Write a detail mechanism for the formation of the product in question 3(1).
3. In the deuterium-labeled compound below predict the product(s) of the elimination of the following elimination reaction and tell whether the alkene formed contains deuterium or not. (20 pts) HAC CH OH H,SO (aq) hear o H2CD NaOCH.CH CHCH OH heat CH3 (iii) Write a detail mechanism for the formation of the product in question 31. 4. Name the following compounds and state the orientation around the double bond (cis/trans or E/Z) (10 pts) HO,
3. In the deuterium-labeled compound below predict the product(s) of the elimination of the following elimination reaction and tell whether the alkene formed contains deuterium or not. (20 pts) HAC CH OHH .SO.( heat HCP, H NaOCH.CH CHCHOH heat CH3 (iii) Write a detail mechanism for the formation of the product in question 30. 4. Name the following compounds and state the orientation around the double bond (cis/trans or E/Z) (10 pts) 0
3. In the deuterium -labeled compound below predict the product (s) of the elimination reactions of the following elimination reaction and tell whether the alkene formed contains deuterium (D) or not. (20 pts) Н.с, сн, OH H2SO&(aq) (i) heat НС NAOCH2CH3 (ii) CH3CH2OH н CH3 heat (iii) Write a detail mechanism for the formation of the product in question 3(i)
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3. In the deuterium-labeled compound below. predict the product(s) of the elimination reaction of the following elimination reaction and tell whether the alkene formed contains deuterium (D) or not. (20 pts) HC CH OH H,SO (aq) heat HCP NaOCH-CH3 CH,CH OH heat Сн, (iii) Write a detail mechanism for the formation of the product in question 300). 4. Name the following compounds and state the orientation around the...
3. In the deuterium-labeled compound below predict the product(s) of the elimination reaction of the following elimination reaction and tell whether the alkene formed contains deuterium (D) or not. (20 pts) HC CH, ОН TH 0 H,SO.(aq) heat D HC NaOCH.CH CH2CH,OH heat CH, (ii) Write a detail mechanism for the formation of the product in question 30). 4. Name the following compounds and state the orientation around the double bond (cis/trans or E/Z) (10 pts) НО. Dr. Denton
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2. Show the step by step mechanism to account for the following transformation. Also predict the major product formed. (20 points) CH3 OH conc. HBO CH₂ H₂CX Br CH₂ H3C CHE H₃C CH Swi condition Br L CH3 CH3 H₃C HC X X
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7. Draw the major product expected in each reaction below. (10 pts) CH3 H3PO4 i. Hас. "CHз heat OH н CH3CH2ONA Hас н CH-CH-он ii CH2CH3 Br 55 °C н Насо. KSH (1 mol equivalent) ii. acetonitrile OTs Pон iv acetonitrile Но.
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6. For the following reactions tell whether they will react under Syl condition (EtOH, heat), SN2 condition (Nal/acetone) or neither. Also indicate the product formed if any. (10 points) Mechanism Product (SN1 or SN2) 11. Tso H₃Ct iv. НАС HC CHE
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5. Predict the eliminations products A and B formed (E-1 mechanism) when 4,4-dimethylhexan- 3-ol is heated with concentrated phosphoric acid. Also, identify the rate determining step and the major product using Zaitsev's Rule? (Mechanism must be shown to receive full points) (20 pts) он conc. H3PO4 CH3 Products A and B нас E-1 condition HzC CH3 4,4-dimethylhexan-3-ol