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31. What is the best term to describe the rearrangement that causes the formation of 2-methyl-2-butanol...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Base...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
1. Which of the following structures is/are a secondary alkyl halide? (a) I and II (b)...
1. Which of the following structures is/are a secondary alkyl
halide? (a) I and II (b) II and V (c) I, II and V (d) IV only (e)
I, II and III 2. Which of the following is/are aprotic solvent(s)?
Choose all correct answers. (a) (b) (c) (d) (e) (f) 3. Which of the
following carbocations, if formed, is (are) likely to undergo
rearrangement through a hydride shift? (a) I (b) II (c) III (d) I
and II (e) II...
led by the base and loving ne relative geometry requirement of the H-atom being a what...
led by the base and loving ne relative geometry requirement of the H-atom being a what is the E2 reaction? group in the E2 General Example: A) gauche B) anti-coplanar C) syn-coplanar D) eclipsed-coplanar KR 25. Which of the carbocations can undergo a 1.2-methyl shift to form a more stable carbocation Como C) 1,3 D) 1,4 A) 2, 3 B) 2,4 26. For the stereospecific reactions below, choose which compound represents the final product: H2(g) Product | Cats Н,0 2-butyne-...
39. What is the major product obtained from the following reaction? Br CH3 (CH3)2CO (CH3)2COH Ol-Bu...
39. What is the major product obtained from the following reaction? Br CH3 (CH3)2CO (CH3)2COH Ol-Bu CH3 CH3 Ol-Bu CH3 CH3 11 III IV A) III B) I C II D IV 40. What must be the starting material of the following reaction? NaOH A B. ОН ОН a. Hori D. ia ОН ОН 41. Which reaction mechanisms are most likely to occur when (R)-2-iodohexane is heated with KOH in acetone? CH, H.C A) Snl and Sn2 B) E1 and...
21) Dehydration of 1-butanol with concentrated sulfuric acid at 140°C results in the formation of mainly trans-2-bu...
21) Dehydration of 1-butanol with concentrated sulfuric acid at 140°C results in the formation of mainly trans-2-butene. According to these results, which of the following conclusions might be valid? A) The reaction undergoes an E2-type elimination mechanism. B) The reaction follows a new mechanism involving the formation of a carbanion intermediate. C) The reaction undergoes an El-type elimination mechanism in conjunction with a hydride shift. D) The reaction undergoes an E2-type elimination mechanism in conjunction with a methyl shift. E)...
HWS 5: Due 10/30/2019 15 points total SN1, SN2, Elimination pt 1 1. (10 pts) For...
HWS 5: Due 10/30/2019 15 points total SN1, SN2, Elimination pt 1 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group C. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e. Draw the product of the...
Propose a mechanism from the reaction in the box NaOH H,CH2CH.CH DMF Use the reaction for...
Propose a mechanism from the reaction in the box
NaOH H,CH2CH.CH DMF Use the reaction for 28-32 28. What is the classification of the alkyl halide? a.) methyl b.) 1° c.) 2° d.) 30 29. Is the base strong or weak? a.) Strong b.) Weak 30. Is the solvent protic or aprotic? a.) Protic b.) Aprotic 31. According to the base and solvent, which substitution mechanism will the reaction undergo? a.) SNI b.) SN2 32. The stereochemistry of the reactant...
+ Fit to page Page view 1. (10 pts) For the following reactions: a. Label the...
+ Fit to page Page view 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group c. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e Draw the product of the reaction, based upon your categorization, remember...
MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1)...
MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) When 1-pentanol is heated with HCI/ZnCl2, 1-chloropentane is the major product. This is an reaction, and is also produced as product. A) SN2, H2 B) SN2, H20 C) SNI, H2 D) SN1, H20 E) E2, H2 1) 2) What metal do Grignard reagents contain? A) pallium B) magnesium C) copper D) lithium E) ruthenium 3) What is the product of the following reaction? 3)...
17) Which of the following is a secondary halide? A) CICH2CH2C(CH3)3 B) CICH2CH2CH(CH3)2 C) (CH3)2CCICH2CH3 D)...
17) Which of the following is a secondary halide? A) CICH2CH2C(CH3)3 B) CICH2CH2CH(CH3)2 C) (CH3)2CCICH2CH3 D) (CH3)3CCHCICH3 E) CICH2C(CH3)CH2CH3 17) What is the IUPAC name of the compound shown below? нс, CH2CH3 С" A) (15,3S)-1,3-dichloro-l-ethyl-3-methylcyclopentane B) (IR,3S)-1,3-dichloro-1-methyl-3-ethylcyclopentane C) (IR.45)-1,4-dichloro-1-ethyl-4-methylcyclopentane D) (IR,3S)-1,3-dichloro-l-ethyl-3-methylcyclopentane E) (IS3R)-1,3-dichloro-3-ethyl-1-methylcyclopentane 18) What type of intermediate is present in the SN2 reaction of cyanide with bromoethane? A) carbocation B) free radical C) carbene D) carbanion E) This reaction has no intermediate 19) Which of the following alkyl chlorides...
2. (1.5 pts) Label the following reagents as Good or Poor Nucleophiles AND as Strong or Weak Bases. OK Na SH 3. (1.5 pt) Predict the productts) of the following reactions, if there are multiple products indicate which, if any, is the major product. Be sure to clearly mark the stereochemistry of chiral carbon atoms and draw multiple products if there is more than one stereoisomer that forms. HCI MeOH H2SO H2 Pd/BaSO4 quinoline 4. (3 pt) For the following...
1. Which of the following structures is/are a secondary alkyl
halide? (a) I and II (b) II and V (c) I, II and V (d) IV only (e)
I, II and III 2. Which of the following is/are aprotic solvent(s)?
Choose all correct answers. (a) (b) (c) (d) (e) (f) 3. Which of the
following carbocations, if formed, is (are) likely to undergo
rearrangement through a hydride shift? (a) I (b) II (c) III (d) I
and II (e) II...
led by the base and loving ne relative geometry requirement of the H-atom being a what is the E2 reaction? group in the E2 General Example: A) gauche B) anti-coplanar C) syn-coplanar D) eclipsed-coplanar KR 25. Which of the carbocations can undergo a 1.2-methyl shift to form a more stable carbocation Como C) 1,3 D) 1,4 A) 2, 3 B) 2,4 26. For the stereospecific reactions below, choose which compound represents the final product: H2(g) Product | Cats Н,0 2-butyne-...
39. What is the major product obtained from the following reaction? Br CH3 (CH3)2CO (CH3)2COH Ol-Bu CH3 CH3 Ol-Bu CH3 CH3 11 III IV A) III B) I C II D IV 40. What must be the starting material of the following reaction? NaOH A B. ОН ОН a. Hori D. ia ОН ОН 41. Which reaction mechanisms are most likely to occur when (R)-2-iodohexane is heated with KOH in acetone? CH, H.C A) Snl and Sn2 B) E1 and...
21) Dehydration of 1-butanol with concentrated sulfuric acid at 140°C results in the formation of mainly trans-2-butene. According to these results, which of the following conclusions might be valid? A) The reaction undergoes an E2-type elimination mechanism. B) The reaction follows a new mechanism involving the formation of a carbanion intermediate. C) The reaction undergoes an El-type elimination mechanism in conjunction with a hydride shift. D) The reaction undergoes an E2-type elimination mechanism in conjunction with a methyl shift. E)...
HWS 5: Due 10/30/2019 15 points total SN1, SN2, Elimination pt 1 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group C. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e. Draw the product of the...
Propose a mechanism from the reaction in the box
NaOH H,CH2CH.CH DMF Use the reaction for 28-32 28. What is the classification of the alkyl halide? a.) methyl b.) 1° c.) 2° d.) 30 29. Is the base strong or weak? a.) Strong b.) Weak 30. Is the solvent protic or aprotic? a.) Protic b.) Aprotic 31. According to the base and solvent, which substitution mechanism will the reaction undergo? a.) SNI b.) SN2 32. The stereochemistry of the reactant...
+ Fit to page Page view 1. (10 pts) For the following reactions: a. Label the Nucleophile (Nu) and whether it is strong or weak b. Label the Electrophile (E) and whether it is primary, secondary, or tertiary and circle the leaving group c. Label the Solvent and whether it is polar protic or polar aprotic d. Categorize each as preferring SN1, Preferring SN2, or could do either e Draw the product of the reaction, based upon your categorization, remember...
MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) When 1-pentanol is heated with HCI/ZnCl2, 1-chloropentane is the major product. This is an reaction, and is also produced as product. A) SN2, H2 B) SN2, H20 C) SNI, H2 D) SN1, H20 E) E2, H2 1) 2) What metal do Grignard reagents contain? A) pallium B) magnesium C) copper D) lithium E) ruthenium 3) What is the product of the following reaction? 3)...
17) Which of the following is a secondary halide? A) CICH2CH2C(CH3)3 B) CICH2CH2CH(CH3)2 C) (CH3)2CCICH2CH3 D) (CH3)3CCHCICH3 E) CICH2C(CH3)CH2CH3 17) What is the IUPAC name of the compound shown below? нс, CH2CH3 С" A) (15,3S)-1,3-dichloro-l-ethyl-3-methylcyclopentane B) (IR,3S)-1,3-dichloro-1-methyl-3-ethylcyclopentane C) (IR.45)-1,4-dichloro-1-ethyl-4-methylcyclopentane D) (IR,3S)-1,3-dichloro-l-ethyl-3-methylcyclopentane E) (IS3R)-1,3-dichloro-3-ethyl-1-methylcyclopentane 18) What type of intermediate is present in the SN2 reaction of cyanide with bromoethane? A) carbocation B) free radical C) carbene D) carbanion E) This reaction has no intermediate 19) Which of the following alkyl chlorides...
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