Balanced reaction: Fe(OH)3(s) + 4HCl(aq) ----> [FeCl4]-(aq) + 3H2O(l) + H+(aq)
Formation of Prussian Blue: 4[FeCl4]-(aq) + 3K4[Fe(CN)6](aq) ----> Fe4[Fe(CN)6]3(s) + 12KCl(aq) + 4Cl-(aq)
We separate the iron hydroxide ppt from the supernatant liquid containing the aluminum complex ion by...
Aluminum ion in solution reacts with water to form aqueous hexaaguaaluminum ()ion. Write this reaction below, remember phases. Aluminum is more likely to form a hydrated complex than the other four ions remaining in solution, because of its relatively small size and high charge To separate the Group B2 ion, the solution first is made basic by adding ammonia. In the presence of this weak base the pH is adjusted to 9-10 and the group B ions form insoluble hydroxides....
Oxalate ion will interfere with the Group D tests after we make the solution acidic. Also, ammonium ion may prevent the precipitation of Group Dcations as hydroxides in sodium hydroxide solution. Thus, must treat the supernatant liquid left after we have precipitated calcium oxalate, in order to destroy any remaining Oxalate or ammonium ions prior to further analysis. To accomplish this, we transfer the solution to a crucible, add concentrated nitric acid and heat the mixture to dryness in a...
d. Suppose you mistakenly acidify the filtrate with HCl instead of with HNO3. What would you obser after completing the halide test, and what would that observation lead you to conclude? Organic Laboratory Technique Primer Sodium Fusions and lon Testing Background: The elements that commonly occur in organic compounds along with carbon, hydrogen, and oxygen, are: nitrogen sulfur, and the halogens. The detection of these latter three elements depends on converting them into water soluble lons (CNS , and X...