1. Derive the second order rate law for the reaction 2 A →P, and an expression...
1. A reaction is second order in[A] and second-order in [B]: Rate,=K[A]^2[B]^2. what are the units of k for this reaction? If the concentration of air decreases by a factor of 2 and the concentration of b increases by a factor of 5 what happens to the rate? 2. for the forward reaction 2NO+Cl2=>2NOCl. determine the rate(m/s)for experiment #4 given [NO]°(M)=0.40M and [Cl2]°z(M)=0?20M. Rate? 3.The following data were collected over time for the forward reaction 2NO2=>2NO+O2 ( 1/[NO2]=100 at 0...
4) Consider the schematic reaction A →P a) If the reaction is one-half order with respect to [A], what is the integrated rate law expression for this reaction? b) What plot would you construct to determine the rate constant k for the reaction? c) What would be the half-life for this reaction? Will it depend on initial concentration of the reactant'?
The rate constant for the second order reaction 2 NO2 ⟶ N2O4 is 2.79 M-1.min-1 at 48oC. If the initial concentration of NO2 is 1.05 M, what is the half-life?
Derive the equation 1/[B] = 1/[B]_0 + kt from the instantaneous rate of reaction in terms of B and rate = k[B]^2. What are the units of k if concentration is expressed in molarity and time in seconds a. For a first order reaction? b. For a second order reaction? c. For a zero order reaction? d. For a reaction that follows the rate equation, rate = k[A] [B]^1/2? The rate law for a reaction only involves the reactant A...
1. The second-order rate constant for self-reaction of hydroxyl radicals 2 OH → H2O + O has the value 1.0786E9 M-1·s-1 at 360.0 K. Compute the half-life of OH radicals at this temperature if the initial concentration is 6.74E-6 M. 3. Calculate the initial rate of a first-order reaction if the concentration of reactant is 0.37 M and the half-life is 4.48 s. Enter the correct numerical value to 2.0% precision. Express scientific notation like 4.29E-15 M·s-1 4. Cyano...
For a first-order reaction, the half-life is constant. It depends only on the rate constant k k and not on the reactant concentration. It is expressed as t1/2=0.693k t 1 / 2 = 0.693 k For a second-order reaction, the half-life depends on the rate constant and the concentration of the reactant and so is expressed as t1/2=1k[A]0. A certain first-order reaction (A→products A → p r o d u c t s ) has a rate constant of 9.30×10−3...
quantum chem A reaction 2 A rightarrow P has a second-order rate law with k = 3. 50 x 10^-4 dm^3 mol^-1 s^-1. calculate the time required for the concentration of A to change from 0. 260 mol dm^-3 to 0.011 mol dm^-3
Suppose that the rate law for an irreversible reaction is Derive the integrated rate expression for CA as a function of time. What would you plot along the y-axis vs. time in order to obtain a linear relationship?
3. A substance reacts according to a second-order rate law. When the initial concentration of the substance is 0.600 M, the half-life is 2.75 s. Calculate the rate constant.
5. The following reaction is a second order irreversible reaction: 2A + 3B2C i. Derive an expression for the rate of change in the concentration of A as a function of reaction time, initial concentrations and a second order rate constant. Solve this differential equation to yield an equation for fractional conversion of A as a function of time The rate constant is 0.02 L mmol min, and the initial concentrations of A, B, and C are 10 mmol/L, 10...