CH,CHE 1.CH,CH,NH, H 2. LIAME 3.HO CHCHCHCI 1. NaN, 2. Hz. Ni CHCH.CHCI 1. NOCN 2.Hy,...
1) Provide structures for A-J in the following roadmap. H NaN CH,NH LAIRL CH,OH (XS) CH,OH SOCI, E A B D Fr, Cafe 1) KOH, HO 2) H0 NH, SOCI: 2) Propose a mechanism for the following transformation, including arrows to describe electron flow, and all intermediates. NaOH HO OH
1. Predict the major produc t for the following reactions. (1) CO2 (2) Ho MgBr H,O SOCI CEN dine Cl OH excess NH Ci (CH3)2CuLi Cl (1 excess CH CH2MgBr Ci (2)H20 SOCI NH2 SOCI OH
Question 4: - CH₂ 1) Hg(OAC), H, 2) NaBH нс CHE Question : Predict the product(s) of the following reaction: 1) BH, . THE 2) HO, NaOH H3C SCH Question 6 Predict the products of each of the following reactions: H3C- CH3 H₂ Ni -CH₃
1. excess CHI 2. Ag2O, H,0 KOHB 150°C NH a) A= a) A= BH(CH3)3 Y B= V B= | #NH(CH3)3 V N-(CH3)2 I b) A= Y Ag-(CH3)3 B= W d) A= V B= CH
6. CH3 Br CCI 7. CH3 Br CH, OH 8. CHE 1. MCPBA 2. CH,OH, H* 9. CH Oso,,H,O, 10. Na, NH 0
Question 1 Using the reagents listed below, propose a sythesis of the larget compound starting from benzene. Euter ye wish to use them. You may assume that all reactions are appropriately worked up and that mixtures of con CI NH A. Cl/FeCl3 B. HNO3/H SO4 C. CH COCIAICI: D. NaNO/HCI E HC1/Cuci F. KCN/CuCN G. H2PO2 H II O/hcat I. II, CrO4 J. 1)LiAlH42)HO K H/Ni L. 1) Mg 2)CO, 3)H,09 M. CH OLH:0 N. (CH4)2S02NaOH 0. CH3OH P. SOCI...
Give the product for the following reaction 1. OH NH 2. CH CH, CH, Br 3. Ho heat + CHCH CHANH-CH-CH-CH, CH.CH NH3 o CH. CH.CH NHS O OH NH2
give major product O 11. Ç(CH3)3 1) CH3CCI, AICI: 2) (CH3)2NH H2, Raney-Ni, heat 12. ÇO Me 1) PhMgBr (2 equiv.) 2) H20, H30 13. CNH2 1) Brz, NaOH, H20 2) CH,CCI, pyridine 14. HNO3 CHO но +н н+он н+он нон CH OH оо 15. H2NCO, 1) (CH3),COCOCOC(CH3)3 Ph -N: C: NH- PhNHNH | 16. CHO HOTH HOH (3 equiv.) H-OH HO+H CH2OH ai
Provide the major product or reagents 1. KOH (1-1) NH 2 CH CHÚCH_Br 3. NHẠNH H., Hy Pd ?? 22 (g-h) NH NO2 (g-k) -NEN OH CI 1. CH 2. Ag,0 3. heat 1. CH! 2. Ag,0 3. heat OH NHA 2? ?? (n-o) CI (p-1) 1. Mg, other 2. CO2 3. H.0, H. CH,CHÁNH, H. A ?? 1. LAIH4 CH,CH,OH, H Осн. 2. H,OH
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...