Question

The reaction between the compound [Fe (H2O).] (NO3)3 and Na (NSC) produces a red ferric thiocyanate complex, [Fe (H2O)-(NSC)]
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Answer #1

since the concentration of water is constant throughout the reaction it will not affect the value of equilibrium constant.

concentration of complex formed as product is 0.016 means that 0.016 moles of each component in the reactant is involved in the reaction to produce the complex .hence

equilibrium concentration of reactants are 0.025-0.016=0.009 and 0.050-0.016=0.034 respectively

we know that the equilibrium constant of a particular reaction is the ratio of product of concentration of product to the concentration of reactants

kc=(0.016*0.016)/(0.009*0.034)

=0.8366

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