Ans:1
We know, according to the ideal gas equation:
PV = nRT
Where P = pressure
V = volume
R = gas constant
T = temperature in K
so, Now, according to question (At constant P)
PV1 = nRT1 ..................(1)
PV2 = nRT2 ..................(2)
diving equation (1) by (2), we get
PV1/PV2 = nRT1/nRT2
V1/V2 = T1/T2
30.0L / V2 = 473K / 278K
V2 = 30.0L * 278 / 473
V2 = 17.4L
Option B is correct answer.
Ans:2
According to the ideal gas equation:
P1V1 = nRT1 ........... (3)
P2V2 = nRT2 ............(4)
Dividing equation (3) by (4), we get,
P1V1/ P2V2 = nRT1 / nRT2
P1V1/ P2V2 = T1 / T2 (as the amount of gas is fixed)
Now, putting the values we get,
760mmHg * 175L / 640mmHg * 198L = 288K / T2 (15 oC + 273 = 288K)
T2 = 288K * 640 *198 / 760 * 175
= 274.4K
We know,
the temperature in Kelvin = the temperature in degree Celcius + 273
so, the temperature in degree Celcius = the temperature in Kelvin - 273
= (274 - 273) oC
=1 oC
hence, option D is the answer.
Ans:3
According to the ideal gas equation:
PV =nRT
n = weight of CO2 / molar mass of CO2
= 25.2g / 44g
= 0.57moles
Value of R in atm = 0.082057 L atm mol-1K-1
Temperature in K = (25+273 )K = 298K
Now, putting values in ideal gas equation,
0.840atm *V = 0.57moles * 0.082057 L atm mol-1K-1 * 298K
V = 16.9L
hence, option C is correct.
Hope this helps!
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