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Application Questions 1. Predict all the products for the following reaction. Which is the major product?...
1.Predict all the products for the following reaction. Which is the major product? Why? + conc....
1.Predict all the products for the following reaction. Which is the major product? Why? + conc. H2SO4 heat OH 2. Give an alcohol that you could use to synthesis each of the following alkenes? din 3.Draw the mechanisms for the following two schemes (two separate mechanisms). Only show the mechanism for the most stable product for each scheme. What is the key difference in the mechanistic steps between these two reactions? ОН ОН conc H2SO4 conc H2SO4 heat heat
Application Questions 1. Predict the product for the following reaction. Which is the major product? Why?...
Application Questions 1. Predict the product for the following reaction. Which is the major product? Why? conc. H2SO4 heat OH 2. What alcohol could you use to synthesis each of the following alkenes? Draw a scheme for each one. 3. Draw the mechanisms for the following two schemes (two separate mechanisms). VWhat is the key difference between these two mechanisms? он conc H2SO4 heat он conc H2SO4 heat
3. Draw the mechanisms for the following two schemes (two separate mechanisms). Only show the mechanism...
3. Draw the mechanisms for the following two schemes (two separate mechanisms). Only show the mechanism for the most stable product for each scheme. What is the key difference in the mechanistic steps between these two reactions? ОН conc H2SO4 heat OH conc H2SO4 heat
1. Predict all the products for the following reaction. Which is the major product? Why? conc....
1. Predict all the products for the following reaction. Which is the major product? Why? conc. H2SO4 heat OH
1. Predict all the products for the following reaction. Which is the major product? Why? conc....
1. Predict all the products for the following reaction. Which is the major product? Why? conc. H2SO4 heat OH
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate...
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: i 1. NaBH, MOH 2. H, H2O 3. conc. H2SO4, heat 1. LiAlH4, THE 2. H, H2O 3. MSCI, Pyr, 0 °C 1. SOCI, EIN -D 2. LAIH, ether 1. Li, hexane 2. i . THE 3. acidic work-up Jone's reagent ОН OH 1. PBT 2. NaCN, THE PH conc. H2SO4 NaCl 0°C conc. HBO OH heat
II. Reactions: Predict the major organic product(s) or write the appropriate reagents/starting materials for the following...
II. Reactions: Predict the major organic product(s) or write the appropriate reagents/starting materials for the following reactions. Indicate stereochemistry and regiochemistry when appropriate. Indicate reactions that are expected to result in a racemic mixture of products DBr 1. Н.О, CHCI он HSO, heat кон 1) вн, THF 3. 2) H202. HO 1) Hg(OAc)2, CH,OH 2) NaBH, OH 5. Br2 SH 6. HIO4 OH THF, H2O "он III. Synthesis: Starting from the alkenyl bromide below, devise a synthesis that produces the...
1. Predict the major product for the following electrophilic addition reactions. Show the mechanism for each...
1. Predict the major product for the following electrophilic addition reactions. Show the mechanism for each reaction. a. catalytic H2SO4 OH b catalytic H2SO4 H2O catalytic H2SO4 но
1. Draw all the products for the following reactions and circle the major product. ОН TsOH...
1. Draw all the products for the following reactions and circle the major product. ОН TsOH OH do H2SO4 Heat
3. Predict the major product (only one product) in each of the following reactions and indicate...
3. Predict the major product (only one product) in each of the
following reactions and indicate the type of mechanism.
3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism Sn2 Sn1 HO HBr moy ng heo 0°C, H2O E2 E1 Mechanism Sn2 Sn1 H2SO4 E2 E1 Mechanism HBr SN2 Sn1 rt, H20 E2 E1 OH
1.Predict all the products for the following reaction. Which is the major product? Why? + conc. H2SO4 heat OH 2. Give an alcohol that you could use to synthesis each of the following alkenes? din 3.Draw the mechanisms for the following two schemes (two separate mechanisms). Only show the mechanism for the most stable product for each scheme. What is the key difference in the mechanistic steps between these two reactions? ОН ОН conc H2SO4 conc H2SO4 heat heat
Application Questions 1. Predict the product for the following reaction. Which is the major product? Why? conc. H2SO4 heat OH 2. What alcohol could you use to synthesis each of the following alkenes? Draw a scheme for each one. 3. Draw the mechanisms for the following two schemes (two separate mechanisms). VWhat is the key difference between these two mechanisms? он conc H2SO4 heat он conc H2SO4 heat
3. Draw the mechanisms for the following two schemes (two separate mechanisms). Only show the mechanism for the most stable product for each scheme. What is the key difference in the mechanistic steps between these two reactions? ОН conc H2SO4 heat OH conc H2SO4 heat
1. Predict all the products for the following reaction. Which is the major product? Why? conc. H2SO4 heat OH
1. Predict all the products for the following reaction. Which is the major product? Why? conc. H2SO4 heat OH
1. Give the major product of the following reactions, write N.R. if no reaction happens. Indicate the stereochemistry if necessary: i 1. NaBH, MOH 2. H, H2O 3. conc. H2SO4, heat 1. LiAlH4, THE 2. H, H2O 3. MSCI, Pyr, 0 °C 1. SOCI, EIN -D 2. LAIH, ether 1. Li, hexane 2. i . THE 3. acidic work-up Jone's reagent ОН OH 1. PBT 2. NaCN, THE PH conc. H2SO4 NaCl 0°C conc. HBO OH heat
II. Reactions: Predict the major organic product(s) or write the appropriate reagents/starting materials for the following reactions. Indicate stereochemistry and regiochemistry when appropriate. Indicate reactions that are expected to result in a racemic mixture of products DBr 1. Н.О, CHCI он HSO, heat кон 1) вн, THF 3. 2) H202. HO 1) Hg(OAc)2, CH,OH 2) NaBH, OH 5. Br2 SH 6. HIO4 OH THF, H2O "он III. Synthesis: Starting from the alkenyl bromide below, devise a synthesis that produces the...
1. Predict the major product for the following electrophilic addition reactions. Show the mechanism for each reaction. a. catalytic H2SO4 OH b catalytic H2SO4 H2O catalytic H2SO4 но
1. Draw all the products for the following reactions and circle the major product. ОН TsOH OH do H2SO4 Heat
3. Predict the major product (only one product) in each of the
following reactions and indicate the type of mechanism.
3. Predict the major product (only one product) in each of the following reactions and indicate the type of mechanism. (3 pts; no partial point) Mechanism Sn2 Sn1 HO HBr moy ng heo 0°C, H2O E2 E1 Mechanism Sn2 Sn1 H2SO4 E2 E1 Mechanism HBr SN2 Sn1 rt, H20 E2 E1 OH
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