Question

Predict the major products of the following reactions, and give the structures of any intermediates. Include stereochemistry where appropriate

Predict the mmge where appropriate НС Br (b) CCI (a) (1) 0, (-78 °C) (2) (CH)S HBr (e) ROOR

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Answer #1

a)Hel c| А H el Mechanism: HLH H Haci -eiro e -CH3 Ης Τ . c. H3C ( ең, el H Reaction processed by formation of stable carbocati

b)

대3 CS HA, IS MINOHBr - CH₃ ROOR Mechanism: ROFOR 2 RO ROH - Br ROH + Br C13 Br Вт - Br HR Br

1.03 (-78) 2. (CH3)2S C013 HE CH₃ Mechanismi -CH3 T CH3 a I-un coor CH₂ :0: He o CH₂ I C=0 ore che Hace H3C he si toon He -CH

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