1. (20 pts) Write the structure of the product of each step of these reactions. Be...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Predict the products of the following reactions. I will rate fast. Thank you in advance! excess NaNH2 THF Br Br H 1. NaNH2 2. CH3CH2Br H2SO4, H20 v MSO. MO H2, Pd/Baso quinoline, CH3OH Na, NH3 Na, NH, 1 equivalent HBr NaNH2 Br (excess) 1. Sia BH, THF 2. H202, NaOH h. HgSO4 H2SO4 H20
In each reaction box, place the best reagent and Conditions from the list below. H C C H Br Br H2, Lindlar catalyst H20, H2SO4, Hgso4 CH3CH2Br HBr 1-equiv BH3/THF HBr 2-equiv CH3CH2CH2Br CH3Br H202/NaOH Br2 1-equiv NaOH NaNH2 Br2 2-equiv
Give the major organic product(s) of the reactions of l-methyl-2-deuteriocyclohexene (D = "H) with the reagents given. Be sure to show all stereoisomers formed, and indicate which isomers are formed in equal and in unequal quantities. CHE 1-methyl-2-deuteriocyclohexene (a) (1) BH, THF: (2) H:03, NaOH, H:0 (b) HBr, AIBN (c) Br, H:0 Give the major organic product(s) of the reactions shown below. Be sure to show all stereoisomers formed, and indicate which isomers are formed in equal and in unequal...
write a major product for each of the following reaction, indicate appropriate stereochemistry 1.(CH3)3COK, (CH3)2COH 2. Brz, cena 2 3. x's NaNH2 ; H20 W 14. HgSO4, H2SO4, H2O ÇI 1. x's NaNH2; H20 * 2. k, NH3, CH3CH2OK 3. KMnO4 , H2SO4, 4 1. B2H, THF; NaOH(aq), H202 2. SOBrą, o 1. H2SO4, A OH 318 , NaNH2 4. H2, Lindlar catalyst 2. HBr, H202 3.(CH3)3COK, (CH3)3COH 4. R-COOH; H30°
In each reaction box, place the best reagent and conditions from the list below. CH3 HBr CH3Br Br2 H2, Lindlar catalyst bromocyclohexane BH3 THF H202, NaOH, H20 H20, H2SO4 excess NaNH2 CH3CH2Br SOC
First we start with ______________and immediately add ______________followed by ______________ work up to give the new functional group ______________. Then treatment with ______________and ______________will give (syn / anti) ______________addition to give the ______________(stereochemistry) ______________(functional group) . The final product can be formed by adding ______________ . Br OH P) CH3CH2ONa, CH3CH2OH Q) (CH3)3COK, (CH3)3COH R) NaNH2, NH3 S) Na, NH3 T) H2 A) NBS B) Br2, CCI4 C) Cl2, CCl4 D) HBr E) HBr, ROOR F) H20 G) Hg(OAc)2, NaOH, H20 H) HgSO4, H2O, H2SO4 ) H30workup)...
18. Which sequence of reagents would be expected to accomplish the transformation of 1-butyne shown below? A) 1)H2O/H2SO4, HgSO4 cat.; B) 1)HBr C)1)H2, Lindlar catalyst; D) )HBr, peroxides; E) O 2) H2, Pt 2) H2, Pt; 2) BH3*THF; 2) NaOH; 2) H2O 3) NaOH 3) H202, NaOH 3) H2, Pt
In each reaction box, place the best reagent and conditions from the list below. In each reaction box, place the best reagent and conditions from the list below. CH3 BH3 THF H20, H2SO4 excess NaNH2 HBr SOCI2 CH3CH2Br H2, Lindlar catalyst H202, NaoH, H20 Br2 bromocyclohexane CH3Br
In each reaction box, place the best reagent and conditions from the list below. H CEC-H H2, Lindlar catalyst CH3CH20i H20, H2SO4, HgSO4 CH3C Br2 2-equiv. CH3CH2CH2Cl BH3/THF NaOH HBr 2-equiv. H202/ NaOH HBr 1-equiv. NaNH Br2 1-equiv