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B) Calculate the boiling point and feeling point of each slution a) 10g of MCI, 100l of us solution b) 10% by mass AL(S ), in







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Answer #1

(a) molality of solution = (10g/95.211g/mol)×(1000/100) = 1.0503 molal

i = 3 ( 1 Mg2+ and 2 Cl-)

∆Tb = i.Kb.m = 3 × 0.512×1.0503 = 1.613

∆Tf = i.Kf.m = 3 × 1.86×1.0503 = 5.86

The boiling point of solution is 101.6℃ and freezing point is -5.86℃ . (Answer)

(b)

10% by mass of Al2(SO4)3

Molality =( 10g/342.151g/mol)×(1000/90) = 0.3247molal

i = 5 ( 2 Al3+ and 3 SO42-)

∆Tb = 5× 0.512 × 0.3247 = 0.8313

∆Tf = 5×1.86×0.3247 = 3.02

The boiling point of solution is 100.83℃ and freezing point of solution is -3.02℃ . (Answer)

(c)

i = 3 ( 2 Na+ and 1 citrate ion)

∆Tb = 3 × 0.512 × 0.10 = 0.1536

∆Tf = 3 × 1.86 × 0.10 = 0.558

The boiling point of solution is 100.154℃ and freezing point of solution is - 0.558℃ . (Answer)

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