(A.) Concentration CuSO4.5H2O = 0.100 M
volume of solution = 25 mL = 0.025 L
moles CuSO4.5H2O needed = (Concentration CuSO4.5H2O) * (volume of solution in Liter)
moles CuSO4.5H2O needed = (0.100 M) * (0.025 L)
moles CuSO4.5H2O needed = 0.0025 mol
mass CuSO4.5H2O needed = (moles CuSO4.5H2O needed) * (molar mass CuSO4.5H2O)
mass CuSO4.5H2O needed = (0.0025 mol) * (249.7 g/mol)
mass CuSO4.5H2O needed = 0.624 g
(B.) According to dilution law,
C1 * V1 = C2 * V2
where C1 = initial concentration of NaOH = 0.125 M
V1 = volume of original solution required
C2 = final concentration of NaOH = 0.075 M
V2 = final volume of solution = 50 mL
V1 = V2 * (C2 / C1)
V1 = (50 mL) * (0.075 M / 0.125 M)
V1 = (50 mL) * (0.6)
V1 = 30 mL
volume of 0.125 M solution of NaOH needed = 30 mL
(C.) aluminum acetate is Al(CH3COO)3
Al(CH3COO)3 (aq) Al3+ (aq) + 3 CH3COO- (aq)
concentration of aluminum ion = concentration of aluminum acetate
concentration of aluminum ion = 0.33 M
concentration of acetate ion = 3 * (concentration of aluminum acetate)
concentration of acetate ion = 3 * (0.33 M)
concentration of acetate ion = 0.99 M
(D.) The balanced chemical reaction is :
NaCl (aq) + AgNO3 (aq) AgCl (s) + NaNO3 (aq)
concentration NaCl = 0.150 M
volume NaCl solution = 50 mL
moles NaCl = (concentration NaCl) * (volume NaCl solution)
moles NaCl = (0.150 M) * (50 mL)
moles NaCl = 7.5 mmol
initial moles Na+ = moles NaCl = 7.5 mmol
initial moles Cl- = moles NaCl = 7.5 mmol
Similarly, moles AgNO3 = 6.8 mmol
initial moles Ag+ = moles AgNO3 = 6.8 mmol
initial moles NO3- = moles AgNO3 = 6.8 mmol
Since less moles of AgNO3 are present, therefore AgNO3 is the limiting reactant
moles AgCl formed = moles AgNO3 consumed
moles AgCl formed = 6.8 mmol
moles Ag+ left = 0
concentration of silver ion after reaction = 0
moles Cl- left = (initial moles Cl-) - (moles Cl- consumed in AgCl)
moles Cl- left = (7.5 mmol) - (6.8 mmol)
moles Cl- left = 0.7 mmol
Total volume = (50 mL) + (40 mL) = 90 mL
concentration of Cl- ion after reaction = (moles Cl- left) / (total volume)
concentration of Cl- ion after reaction = (0.7 mmol) / (90 mL)
concentration of Cl- ion after reaction = 0.0078 M
concentration of Na+ ion after reaction = (moles Na+) / (total volume)
concentration of Na+ ion after reaction = (7.5 mmol) / (90 mL)
concentration of Na+ ion after reaction = 0.083 M
concentration of NO3- ion after reaction = (moles NO3-) / (total volume)
concentration of NO3- ion after reaction = (6.8 mmol) / (90 mL)
concentration of NO3- ion after reaction = 0.076 M
(E.) According to dilution law,
C1 * V1 = C2 * V2
where C1 = initial concentration of Na3PO4 = 0.5 M
V1 = volume of original solution = 1 drop
C2 = final concentration of NaOH = 0.1 M
V2 = final volume of solution
V2 = V1 * (C1 / C2)
V2 = (1 drop) * (0.5 M / 0.1 M)
V2 = (1 drop) * (5)
V2 = 5 drops
drops of water added = (final volume) - (initial volume)
drops of water added = (5 drops) - (1 drop)
drops of water added = 4 drops
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