5. Predict the organic products of the following SN2 reactions, using arrows to show the flow...
2. (4 pts) Using the curved arrows, provide a reasonable mechanism for the following reactions. Br Н Br2 Нзс Нзс Br Нас Br Br2 Н-о Hас Но Н I
2. Draw the mechanism of the following reactions using arrows to show the flow of electrons а. Br 2 eq. NaNH2 N Br b. p-TSOH is a strong acid like H2SO OH p-TSOH Гон Cн.Cl A d. NaBH Но D но. е. Н,о* он но н
Question 5 Predict the major and minor products for the following reactions: а) NaSH Hас b) Br NaOEt Question 6 Predict the major and minor products for the following reactions: a) NaOEt CHa OTs With Tosylate (OTs)
General Organic Chemistry Homework I) Draw mechanisms and products for the following SN2 reactions. Use arrows to show electron movement. The reaction of 1-bromobutane with: a) OH- b) CH,CH2OK Na d) e) NH
5. Predict the major organic products of the following reactions. Show all asymmetric carbons with wedgeldash notation (i.e., as shown in the starting material). If a reaction produces a racemic mixture, show only one of the enantiomers produced. Carefully note the requested reaction mechanism for each reaction. (20 pts) NaOCH3 CH3OH SN2 Br CH3OH SN1 Br NaOCH3 CH3OH E2 Show Zaitsev product Br CH3OH Br E1
Evening SN2 vs. E2 Homework Predict the major product(s) expected for each of the following reactions. Remember to indica stereochemistry, when appropriate. If no reaction is expected, write NR. a. CH3CN opothe Na t-BuO t-BuOH Rrot b. C. H3C d. H3C Br e. OH EtOH Pro NaN3 OH acetone poic NaOH Stos nlphe h. OTS EtOH pokc
1. For each of the following reactions, provide the structure of the major organic product(s). Show all the relevent stereochemistry clearly. who CH2OH reflux CH2CH3 Na SET Br DMSO, 20 °C I- A to CH2CH3 CH3 H- EtOH OTS 20 °C Me NaNH2 NH2 DMSO dilute solution of substrate 2. Complete each of the following reaction by providing reagents and conditions (solvent. temperature, concentration, etc.) so that the product shown will be the major one. Note: for c), two steps...
Predict the major organic products formed in the following reactions. Be certain to indicate stereochemistry in your products if it is important. H2 Pd/C HCI H2O H2SO4 Br2 Draw a stepwise, detailed mechanism for the acid-catalyzed hydration reaction in question 2 above. Use curved arrows to indicate the flow of electrons. (Note: use hydronium ion, H307, in your mechanism to indicate “acidic water”).
Predict the major organic products formed in the following reactions. Be certain to indicate stereochemistry in products if it is important. H2O H2SO4 Br2 3. Draw a stepwise, detailed mechanism for the acid-catalyzed hydration reaction in question 2 above. Use curved arrows to indicate the flow of electrons. (Note: use hydronium ion, H:07, in your mechanism to indicate "acidic water"). (6 pts)