Cp is always greater than Cv because heat added at constant pressure will change internal energy and do work but at constant volume work done is zero and added heat will only increase internal energy.
No, Cp is less than Cv is not valid for liquids, it is always greater than or equal to Cv.
A. Compute Cp-Cv for a gas described by the equation of state p= RT/V-b B. For this equation of state, does a measurement of Cp-Cv reveal non-ideal behavior (give ≈ 1 sen- tence justification why or why not)?
Show that for an ideal gas Cp=yR/(y-1), Cv=R/(Y-1) and Cp-Cv=R
Which of the following statements are true about the relationship between C P,mand CV, m? Check all that apply. o CP,m can be greater or less than C v.m for a gas. CP.mis always greater than C V.m for a liquid. CP,mis always greater than C v,m for a gas. CP,m can be greater or less than C v,m for a liquid.
Useful constant: R-0.08315L.bar/K.mol, 0.08206L.atm/K.mol or 8.314J/K.mol, Cv(any monoatomic gas) 3R/2 and Cp-Cv+ R for an ideal gas. Section I 1. Assuming that CO2 is an ideal gas, calculate ASo (in the unit, J K:1) for the following process 1 CO (g, 298 K, 1 bar) 1 CO (g, 1000 K, 1 bar) Given that: Cv 18.334 + 42.262 x 103 T - 142.4 x 10-7 T2 (where Cv is in of JK-1)
For a gas compressor compresses gas (Cv= 718 J/KgK and Cp= 1005 J/KgK) adiabatically from 1 bar and 15 ºC to 10 bar with an isentropic efficiency of 0.89. The gas flow rate is 5 kg/s. Calculate the temperature after compression and the power input
For a real gas obeying van der Waals equation CP-CV is a)R b)zero c) > R d)< R
2. One mole of an ideal gas, CP - (7/2)R and CV - (5/2)R, is compressed adiabatically in a piston/cylinder device from 2 bar and 25°C to 7 bar. The process is irreversible and requires 35% more work than a reversible, adiabatic compression from the same initial state to the same final pressure. What is the entropy change of the gas?
Can you help me with these? 23. Show that the general thermodynamic relation between the constant-pressure heat capacity (Cp) and constant-volume heat capacity (Cv) can be given as: 24. Calculate the ratio of the number of molecules in the lowest two rotational states in a gas of H2 at 50 K (take the inter-atomic distance 1.05 Å)
One mole of an ideal gas with CP = (7/2)R and CV = (5/2)R expands from P1 = 8 bar and T1 = 630 K to P2 = 1 bar. Take the value of R as 8.314 J·mol-1·k-1. At constant volume (assume mechanical reversibility), find the value of W, Q, ΔU, and ΔH? rt.)
1 - Solve the items of applied chemical thermodynamics Determine a relationship between Cp and the PVT properties of any substance. Tip: Start from the definition of Cp and fundamental relationships. If the previous substance behaves as the ideal gas, show that Cp and Cv are independent of the pressure. What is the relationship between Cp and pressure for a compressed liquid if the isobaric expansion coefficient is independent of pressure. If a gas can be described by the Clausius...