Option D
Since there are no ions in ionization spehre.
But in remaining all have ions in ionization spehre.
2c. Which of the following complexes do not ionize in solution? Give a reason for your...
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
Part A (2 marks) In the following pairs of complexes, which do you expect to have a larger ligand field splitting parameter Ao? Why? Explain? i) [Fe(NH3)612+ or [Fe(NH3). 13+ ii) (Co(CN)613- or [Rh(CN)613- Part B (3 maks) In the following pairs of complexes, which do you expect to be more labile? Why? Explain? ) [Cr(NH3)613+ or [Mn(NH3)6]3+ ii) (Co(CN)613- or [Rh(CN)613- ii) [Cr(NH3).]3+ or [V(NH3).]2+
1. Name the following transition metal complexes AND give the coordination number for each metal in the complex ion: Name Coordination # (a) K[Fe(CN).] (b)Ks[Fe(ox).] (c) Cr(en).]C13 (d) (Cr(NH3):(HO)](NO3) (e)ky [Cr(NH3),Cla]
For each of the following transition metal complexes, determine the oxidation state of the metal, its coordination number, and the number of d electrons on that metal. (a) RuO4 (b) (CO(NH3).]3+ (c) [Cr(H2O).]8+ (d) Cr(H2O)3Cl2 (e) [Fe(H2O).]3+ (1) (Co(NH3).]2+ (9) MOCI (h) (Pt(CN)4]2- () [Mn(H2O).]2+ (1) Re(CO).Br (k) (Ag(CN 2] (1) [ReH9]?
Which of the following complexes has the largest crystal field splitting of the d orbitals? A. [Fe(H2O)6]3+ B. [FeF6]3– C. [Fe(NH3)6]3+ D. [FeI6]3– E. [Fe(CO)6]3+
a short answer is fine for each
Predict which of the following complexes in each pair will produce the greater splitting of the d orbitals. Explain your choice in each case. [V(H_2 O)_6]^2+ or [V(H_2 O)_6]^3+ [Cr(CN)_6]^3- or [Cr(NH_3)_6]^3+ [Rh(CN)_6]^3- or (Co(CN)_6)^3- [TiF_6]^3+ or (Ti(H_2 O)_6]^3+ [Co(NH_3)_5F]^2+ or [Co(NH_3)_5Br]^2+ [Fe(NH_3)_6]^3+ or [Fe(NMe_3)_6]^3+ cis-[Pd(NH_3)_2CI_2] or cis-[Pt(NH_3)_2CI_2] [Fe(en)_3]^3+ or [Co(en)_3]^3+, where en = 1, 2-ethylenediamine [CoCl_4]^1- or [Co(CN)_6]^3-
1. Predict the molecular geometry of the following complexes, and determine whether each will be diamagnetic or paramagnetic: (a) [Fe(CN)614- (b) [Fe(C2O4)314- (C) [Zn(NH3)4]2+ (d) [Mo(CO)6] (e) [Rh(NH3)4]+
please answer question
12. For each pair of complexes, predict which will have the larger ligand field splitting. Justify your choices. a. [NiCl4] or [NiClo]4- b. [PtF6]2- or [Pt(CN)6]2- c. [Ru(NH3).]2+ or [Ru(NH3)6]3+
thanks in advance
In which of the following complexes does the transition metal have a de configuration? Select one: O a. Cu(H20)62- O b. PtCl42- O c. Ni(CO) O d. Fe(CN) O e. Zn(NH3)42- Which of the following complexes has inkade somers Select one: O a. [Ni(H20);(SCN)]SO, O b. [Ni(NH3),Clą]A! c. [Ni(NH3),CINO, d. [Ni(H20)ŚCI)(SCN); e. [Ni(H20).CICI O What is a general formula for octahedral complexes that exhibit mer - fac isomerism? (M = metal; A, B and C = ligands)...
5. For each of the following transition metal complexes, give (i) the d-electron count, (ii) the approximate shape of the complex, and (iii) an energy level diagram showing the splitting and filling of the d-orbitals. (a) [Os(CN)6]3- (b) cis-PtCl2(NH3)2 (c) [Cu(NH3)4]*