(R)-2-butanol Tetrahedral Fischer (H vert.) Fischer (H horz.) Skeletal (S)-2-chlorobutane Tetrahedral Fischer (H vert.) Fischer (H...
2. Draw a tetrahedral representation of the following compounds; a) R-2-chlorobutane c) S-2-butanol b) R-2-pentanol d) Meso form of 1,3-Dimethyl cyclohexane
3. Assign R or S configuration on all chirial centers in each of the given Fischer projections. Then, draw the perspective drawing for each structure in the boxes below. Take particular care to indicate stereochemistry properly. 0 он HO- OCH HECH2CH2C HC Br HO H- I W OH H- a) CH₂ 6 CH₂OH OCH d) CH3 Perspective drawings:
3. Assign R or S configuration on all chirial centers in each of the given Fischer projections. Then, draw the perspective drawing for each structure in the boxes below. Take particular care to indicate stereochemistry properly. 0 он HO- OCH HECH2CH2C HC Br HO H- I W OH H- a) CH₂ 6 CH₂OH OCH d) CH3 Perspective drawings:
1. a. Write the structure of R,S,R,R,S-2,3,6-tribromo-4,5-dichlorohepta b. (R )-2-butanol, shown below is converted to a chiral iodide by reacting with Show the mechanism involved in the reaction and state configuration of the H3CH2C to 2. Show the products of the following reactions and identify the number of possible stereoisomers that can be produced. CH CH3 CH 1.BH3 2. NaOH, H202 3. Cortisone is a natural steroid that can be isolated from the adrenal cortex. It has anti of inflammatory...
(3) L1150 2. Draw the Fischer projections of the following compounds and assign (R) or (S) for chiral carbon atom. (30') СН3 (2) PH (1) (R)-2-pentanol (4) (S)-(1-bromoethyl)benzene (3) (S)-CH2OH-CHOH—CH NH (5) 2-methyl-3-chloropentane 9) (2R,3R,4S)-2,3-dibromo-4-chlorohexane
5. For the structure, CHO НЕОН H+OH CH,OH (a) Draw all the stereoisomers. (b) Label structure as chiral or achiral. (c) Assign each chiral center as (R) or (S). (d) Give the relationships between the stereoisomers (enantiome (e) Label any meso compounds. 6. Give the structures of the following compounds. Classify the com primary, secondary, or tertiary halide if possible. (a) Sec-butyl chloride (b) Isobutyl bromide (c) Chloroform (d) Tert-pentyl iodide (c) 2,2,2-trichloroethanol (f) Methylene chloride
1. Consider the following Fischer projection formulas of 3-amino-2-butanol. Decide which pairs of the formulas are related as enantiomers, which are related as diastereomers, and which represent identical molecules. Assign R or S absolute configuration to C2 and C3 for each structure, and then decide. List your results by letters in the spaces provided below. (5 pts) CH2CH3 O CH3CH2 - NH căH HS CH2CH3 H. NH2 SH CH3CH2CH CH,CH2 C- NH, SH Enantiomeric pairs: Diastereomeric pairs: Identical molecules: